Effects of post-printing heat treatment on the microstructure and mechanical properties of a wire arc additive manufactured 420 martensitic stainless steel part

TLDR: In this paper, microstructural features and mechanical properties of a wire arc additively manufactured 420 martensitic stainless steel were investigated in as-printed and heat-treated conditions.

Abstract: In this study, microstructural features and mechanical properties of a wire arc additively manufactured 420 martensitic stainless steel were investigated in as-printed and heat-treated conditions. Initial microstructural investigations on the as-printed part revealed the formation of residual δ-ferrite during the solidification process, which is known as a deleterious phase to both mechanical and corrosion performance of stainless steels. To remove the residual δ-ferrite and obtain a fully martensitic microstructure, the as-printed samples were subjected to different austenitizing temperatures of 950, 1050, 1150, and 1300 °C. Austenitizing at 1150 °C was selected as the optimum cycle due to removal of undesirable phases, such as δ-ferrite and carbides, resulting in a fully martensitic microstructure. Following the austenitizing heat treatment, the samples were tempered at different temperatures including 200, 300, 400, 500, and 600 °C. Increasing the tempering temperature was found to vary the size, morphology, and distribution of chromium carbides precipitated during the tempering process. Although, tempering at lower temperatures (200 and 300 °C) decreased the hardness due to the formation of tempered martensite and stress relieving of the structure, the intermediate temperature of 400 °C increased the hardness value by virtue of the formation of carbides at optimum size and distribution. However, tempering at 500 and 600 °C decreased the hardness as compared to 400 °C due to intergranular segregation and coarsening of carbides. The results of uniaxial tensile testing were consistent with the hardness measurements and confirmed that the tempering temperature of 400 °C led to the optimal combination of strength and ductility ascribed to the formation of fine and homogenously distributed chromium carbides embedded in a moderately tempered martensitic matrix.