Journal ArticleDOI
Electrochemical and optical properties of a redox-active Cu(II) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand
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TLDR
A new redox-active ligand, tris(4-(pyridin-4-yl)phenyl)amine (Npy3), has been synthesised, and incorporated into the coordination framework [Cu(Npy 3)Cl2]·DMF, enabling chemical oxidation of the framework.Abstract:
A new redox-active ligand, tris(4-(pyridin-4-yl)phenyl)amine (Npy3), has been synthesised, and incorporated into the coordination framework [Cu(Npy3)Cl2]·DMF. The monoradical cation of the ligand is readily accessible, thus enabling chemical oxidation of the framework. The novel Npy3 ligand has significant potential as a structural motif for the development of multifunctional frameworks.read more
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Exploiting redox activity in metal-organic frameworks: concepts, trends and perspectives.
TL;DR: This feature article highlights the latest developments in experimental, theoretical and computational concepts relevant to redox-active MOFs, including new solid state electrochemical and spectroelectrochemical techniques that have great utility in this field.
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Redox-active metal–organic frameworks for energy conversion and storage
TL;DR: In this article, the authors review progress over the past 5 years in the study of electroactive metal-organic frameworks with redox activity promoted by different strategies: (i) redox-active metals; (ii) redoxide-active organic linkers; (iii) host-guest interactions; and (iv) charge-transfer frameworks.
Journal ArticleDOI
A Zn-MOF constructed from electron-rich π-conjugated ligands with an interpenetrated graphene-like net as an efficient nitroaromatic sensor
Yang Yi,Kang Shen,Jun-zhong Lin,Yong Zhou,Qiao-yun Liu,Cheng Hang,Hani Nasser Abdelhamid,Zhen-qin Zhang,Hong Chen,Hong Chen +9 more
TL;DR: In this article, a novel zinc-based luminescent metal-organic framework (Zn-MOF) was successfully constructed based on a designed flexible and electron-rich N-involved linker (HL = 4-(bis(4-(pyridin-4-yl)phenyl)amino)benzoic acid).
Journal ArticleDOI
Redox tunable viologen-based porous organic polymers
Carol Hua,Bun Chan,Aditya Rawal,Floriana Tuna,David Collison,James M. Hook,Deanna M. D'Alessandro +6 more
TL;DR: In this paper, the use of an organic donor-acceptor polymer containing a viologen electron acceptor and triarylamine electron donor as a platform in the development of multifunctional materials is presented.
References
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Journal ArticleDOI
Organic Electroluminescent Diodes
Ching Wan Tang,Steven A Vanslyke +1 more
TL;DR: In this article, a double-layer structure of organic thin films was prepared by vapor deposition, and efficient injection of holes and electrons was provided from an indium-tinoxide anode and an alloyed Mg:Ag cathode.
Journal ArticleDOI
ShelXle: a Qt graphical user interface for SHELXL
TL;DR: ShelXle is a user-friendly graphical user interface forSHELXL that combines an editor with syntax highlighting for SHELXL-associated files with an interactive graphical display for visualization of a three-dimensional structure.
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The Class II/III Transition in Triarylamine Redox Systems
Christoph Lambert,Gilbert Nöll +1 more
TL;DR: The mixed-valence character of a set of six bistriarylamine derivatives with varying π-electron spacers has been investigated in this paper, where the distances of triaryamine redox centers vary from 0.5 nm (N,N, N‘,N...
Journal ArticleDOI
Organic mixed-valence compounds: a playground for electrons and holes.
TL;DR: The goal of this Review is to give an overview of the last decade in organic mixed valence chemistry and to elucidate its impact on modern functional materials chemistry.