Journal ArticleDOI
Electrochemical behavior of the molybdotungstate heteropoly complex with neodymium, K10H3[Nd(SiMo7W4O39)2] · xH2O in aqueous solution
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In this article, the electrochemical behavior of the title compound (denoted Nd(SiMo7W4)(2)(13-)) in aqueous solution has been studied using cyclic voltammetry, sampled dc voltammetrics, differential pulse voltameters and bulk electrolysis with coulometry.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1996-05-10. It has received 70 citations till now. The article focuses on the topics: Differential pulse voltammetry & Cyclic voltammetry.read more
Citations
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Electrochemical Properties of Polyoxometalates as Electrocatalysts.
Journal ArticleDOI
Polyoxometalates: Very large clusters - Nanoscale magnets
Journal ArticleDOI
Ultrastable Polymolybdate-Based Metal–Organic Frameworks as Highly Active Electrocatalysts for Hydrogen Generation from Water
Jun-Sheng Qin,Dong-Ying Du,Wei Guan,Xiangjie Bo,Yafei Li,Liping Guo,Zhong-Min Su,Yuan-Yuan Wang,Ya-Qian Lan,Ya-Qian Lan,Hong-Cai Zhou +10 more
TL;DR: As a 3D hydrogen-evolving cathode operating in acidic electrolytes, NENU-500 exhibits the highest activity among all MOF materials and maintains their electrocatalytic activities after 2000 cycles.
Journal ArticleDOI
Self-assembly of nanometer-scale [Cu24I10L12]14+ cages and ball-shaped Keggin clusters into a (4,12)-connected 3D framework with photoluminescent and electrochemical properties.
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Self-assembly of organic-inorganic hybrid materials constructed from eight-connected coordination polymer hosts with nanotube channels and polyoxometalate guests as templates.
TL;DR: Two polyoxometalate-templated organic-inorganic hybrid porous frameworks, namely, [Cu2(H2O)2(bpp)2Cl][PM12O40], were self-assembly obtained and structurally determined by elemental analyses, inductively coupled plasma analyses, infrared spectroscopy, and single-crystal X-ray diffraction analyses.
References
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Heteropoly and Isopoly Oxometalates
TL;DR: A survey of polyoxometalates can be found in this paper, where the authors survey the chemistry, structures, and applications of these species, as well as their applications in inorganic chemistry.
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Highly oxidation resistant inorganic-porphyrin analog polyoxometalate oxidation catalysts. 1. The synthesis and characterization of aqueous-soluble potassium salts of .alpha.2-P2W17O61(Mn+.cntdot.OH2)(n-10) and organic solvent soluble tetra-n-butylammonium salts of .alpha.2-P2W17O61(Mn+.cntdot.Br)(n-11) (M = Mn3+,Fe3+,Co2+,Ni2+,Cu2+)
David Keith Lyon,Warren Kenyon Miller,Thomas Novet,Peter J. Domaille,Eric R. Evitt,David W. Johnson,Richard G. Finke +6 more
Journal ArticleDOI
Electrocatalytic reduction of nitrite and nitric oxide to ammonia with iron-substituted polyoxotungstates
James E. Toth,Fred C. Anson +1 more
TL;DR: In this paper, it was shown that one of the positions normally occupied by a tungsten cation is occupied instead by an iron cation for the electroreduction of nitrite to ammonia, and that the catalyzed reduction does not produce hydroxylamine as an intermediate and appears to depend upon the ability of the multiply reduced heteropolytungstates to deliver electrons to the NO group bound to the iron center in a concerted multiple-electron step.
Related Papers (5)
Electrochemical Properties of Polyoxometalates as Electrocatalysts.
Introduction: Polyoxometalates-Multicomponent Molecular Vehicles To Probe Fundamental Issues and Practical Problems.
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
Michael T. Pope,Achim Müller +1 more