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Electrochromism in sputter deposited W1-y MoyO3 thin films

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TLDR
In this paper, the electrical properties of tungsten-molybdenum oxide (W1y MoyO3) thin films were investigated and the films were deposited on indium tin oxide covered glass by reactive DC sputtering from tungstein and molybbenium targets.
Abstract
Electrochromic (EC) properties of tungsten-molybdenum oxide (W1-y MoyO3) thin films were investigated The films were deposited on indium tin oxide covered glass by reactive DC sputtering from tungsten and molybdenum targets Elemental compositions of the W1-y MoyO3 films were determined by Rutherford back scattering Voltammetric cycling was performed in an electrolyte of 1 M LiClO4 in propylene carbonate An increase in molybdenum content in the EC films caused both a shift towards higher energies and a lowering of the maximum of the optical absorption band, as compared with WO3 EC films Durability under electrochemical cycling was diminished for W1-y MoyO3 EC films

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Citations
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Journal ArticleDOI

Electrochromic materials and devices for energy efficiency and human comfort in buildings: A critical review

TL;DR: Electrochromic (EC) materials can be integrated in thin-film devices and used for modulating optical transmittance as discussed by the authors, and have been used in large-area glazing (windows and glass facades) in order to create buildings which combine energy efficiency with good indoor comfort.
Journal ArticleDOI

Electrochromic W1–x–yTixMoyO3 Thin Films Made by Sputter Deposition: Large Optical Modulation, Good Cycling Durability, and Approximate Color Neutrality

TL;DR: In this article, the authors show that three-component mixed-oxide thin films are able to combine a midluminous transmittance modulation with good color neutrality and durability under extended electrochemical cycling.
Journal ArticleDOI

Advances in electrochromic device technology : Multiple roads towards superior durability

TL;DR: In this article, the authors survey recent efforts related to electrochromic films of W oxide and Ni oxide and show that electrochemical pretreatment of films in a liquid electrolyte can significantly improve durability, electrochemical posttreatment can rejuvenate degraded films, mixed oxides can have better durability, and lifetime prediction is possible.
Journal ArticleDOI

Optical, structural and electrochromic properties of sputter-deposited W-Mo oxide thin films

TL;DR: In this article, a series of characterization techniques, including impedance spectroscopy, spectroscopic ellipsometry, Raman Spectroscopy and atomic force microscopy, were used to study optical spectra, optoelectronic properties, and film structure.
References
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Journal ArticleDOI

Electrochromic tungsten oxide films: Review of progress 1993–1998

TL;DR: In this article, the progress that has taken place since 1993 with regard to film deposition, characterization by physical and chemical techniques, optical properties, as well as electrochromic device assembly and performance is reviewed.
Journal ArticleDOI

Optical and photoelectric properties and colour centres in thin films of tungsten oxide

TL;DR: In this paper, the optical absorption spectra of amorphous and crystalline thin Wo3 films have been measured in the temperature range 110° to 500°K and the temperature coefficient of the band edges was found to be − 5.0 × 10−4 eV/°K.
Journal ArticleDOI

Electrochromics for smart windows: Oxide-based thin films and devices

TL;DR: In this article, the authors present a detailed review of the state-of-the-art for electrochromics and its applications in smart windows and provide ample references to current literature of particular relevance.
Proceedings ArticleDOI

SIMNRA, a simulation program for the analysis of NRA, RBS and ERDA

TL;DR: SIMNRA as discussed by the authors is a Microsoft Windows 95/Windows NT program with fully graphical user interface for the simulation of non-Rutherford backscattering, nuclear reaction analysis and elastic recoil detection analysis with MeV ions.
Journal ArticleDOI

A Novel Electrophotographic System

TL;DR: A novel electrophotographic system is described which consists of a thinFilm of a transition metal oxide and a thin film photoconductive layer sandwiched between a pair of electrodes, which forms a visible image when an electric field is applied across this composite structure.
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