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Electrophoretic deposition and sintering of thin/thick PZT films

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TLDR
In this paper, a 10-μm PZT film was formed from the same starting powder and exhibited a polarization hysteresis equivalent to that of a bulk sample, with a remnant polarization of 33μC−cm−2.
Abstract
Electrophoretic deposition (EPD) is a simple, rapid, and low cost method for forming dense lead zirconate titanate (PZT) films down to 5 μm from particulate precursors. The three main steps of this process are: (1) formation of a charged suspension of the starting PZT powder; (2) deposition of the powder particles on an electrode under the influence of a dc electric field; and (3) fluxing and constrained sintering of the resulting particulate deposit at 900°C to form a dense continuous film. A 10 μm film formed using this process exhibited a polarization hysteresis equivalent to that of a bulk sample formed from the same starting powder, with a remnant polarization of 33 μC cm−2.

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Journal ArticleDOI

A review on fundamentals and applications of electrophoretic deposition (EPD)

TL;DR: In this article, a review of the fundamental aspects of electrophoretic deposition technique, factors influencing the deposition process, kinetic aspects, types of EPD, the driving forces, preconditioning electrophoreic suspension, stability and control of suspension, mechanisms involved in EPD and drying of deposits obtained by EPD are discussed.
Journal ArticleDOI

Cathodic electrodeposition of ceramic and organoceramic materials. Fundamental aspects

TL;DR: In this article, a review of recent developments in the electrodeposition of ceramics and organoceramic materials is presented, which includes mass transport, accumulation of particles near the electrode and their coagulation to form a cathodic deposit, and interparticle forces that govern colloidal stability in the absence and presence of processing additives.
Journal ArticleDOI

Fabrication of Dense Zirconia Electrolyte Films for Tubular Solid Oxide Fuel Cells by Electrophoretic Deposition

TL;DR: In this paper, a simple suspension chemistry (8-mol%-yttria-stabilized zirconia particles in acetic acid) yields films of similar quality to those from conventional approaches (such as electrochemical vapor deposition), but at potentially much less expense.
Journal ArticleDOI

Electrophoretic deposition of ceramic materials for fuel cell applications

TL;DR: In this paper, a solvent-dispersant-binder medium for electrophoretic deposition of LSGM, LSCF, YSZ and CGO was proposed.
References
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Journal ArticleDOI

Electrophoretic Deposition (EPD): Mechanisms, Kinetics, and Application to Ceramics

TL;DR: In this article, a method of determining the Hamaker constant of suspended particles is developed by modeling the relationship between the particle inter-action energy and the suspension stability, and a three-probe dc technique is used to map the voltage profile around the depositing electrode and the results are used to explain discrepancies between the calculated and experimentally observed voltage drops during deposition.
Journal ArticleDOI

High‐Temperature Discharges in Ferroelectric Ceramics

TL;DR: In this paper, it was shown that at constant temperature near 350°C the discharge decays with time as the sum of two exponentials, falling to half-maximum in periods of the order of one half hour.
Proceedings ArticleDOI

Electrophoretic deposition of PZT ceramic films

TL;DR: In this paper, the effect of the incorporation of a sintering aid on the films is examined, and the results show that the pyroelectric coefficient of undoped lead zirconate titanate thin films has a pyrophoresis coefficient of 1.28/spl times/10/sup -5/ Pa/sup −1/2/
Proceedings ArticleDOI

Thin/thick piezoelectric films by electrophoretic deposition

TL;DR: In this article, the use of EPD for forming fully dense Lead Zirconate Titanate (PiT) films of twenty microns and less was discussed, and three main steps as applied to PZT are covered: 1. Formation of a charged SUSCi15IOfl of the startingsub-micron PiT powder. 2. Deposition of the powder particles on an electrode under the influence of a l)C electric field. and3. fluxing and constrained sintering of the resulting particulate deposit to form a dense continuous fil
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