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Journal ArticleDOI

EPR and optical studies of microwave synthesized glasses containing VO2+ ions: Meta and pyrophosphate regime

TLDR
In this article, the electron paramagnetic resonance (EPR) spectra of vanadyl ions in the glasses exhibit a hyperfine structure and an increase in the ratio of Delta g(parallel to)/Delta g(perpendicular to) with an increase of V2O5 content shows that the tetragonal nature of the V4+O6 complex is enhanced.
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This article is published in Journal of Alloys and Compounds.The article was published on 2017-02-25. It has received 17 citations till now. The article focuses on the topics: Electron paramagnetic resonance & Hyperfine structure.

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Synthesis, physical, optical, structural and radiation shielding characterization of borate glasses: A focus on the role of SrO/Al2O3 substitution

TL;DR: In this paper , glass samples with the compositions (30-x)SrO-xAl 2 O 3 -68B 2 O3 -2V 2 O 5 (x = 5, 7.5, 10, 12.5 and 15 mol %) coded as SABV0 - 4 were prepared by the melt-quenching technique and analyzed for their optical, structural, physical, and radiation shielding features.
Journal ArticleDOI

Role of Er3+ and Bi3+ ions on thermal and optical properties of Li2B4O7 glasses: Structural correlation

TL;DR: In this paper, the effect of Er2O3/BiCl3 on their physical, thermal, and optical properties was investigated and it was shown that the optical properties of both the investigated glass systems exhibit composition dependent trends and the properties are critically dependent on polarizabilities and ionicity of the dopant ions.
Journal ArticleDOI

Theoretical study of local structures and EPR parameters for xV 2 O 5 -(100−x)[0.8NaPO 3 -0.2ZnO]: V 4 + glasses at different concentrations

TL;DR: In this paper, the electron paramagnetic resonance parameters and local structures for V4+ in xV2O5-(100−−x)[0.8NaPO3-0.2ZnO] glasses are theoretically investigated by using the perturbation formulas for tetragonally compressed octahedral 3d1 clusters.
Journal ArticleDOI

Theoretical investigations on the EPR parameters and local structures for V4+ in alkali niobium borate glasses

TL;DR: In this paper, the perturbation formulas of EPR parameters for tetragonally compressed octahedral 3d1 clusters were derived from the quasi-linear concentration variations for covalency factor N, tetragonal compression ratio ρ and core polarization constant κ with only three adjustable coefficients.
References
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BookDOI

Amorphous and liquid semiconductors

Jan Tauc
TL;DR: In this article, the nature of the amorphous state and the electronic properties of the Amorphous Semi-conductors have been investigated in the context of liquid semiconductors.
Journal ArticleDOI

Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors

TL;DR: In this article, the experimental evidence concerning the density of states in amorphous semiconductors and the ranges of energy in which states are localized is reviewed; this includes d.c and a.c. conductivity, drift mobility and optical absorption.
Journal ArticleDOI

Disorder and the Optical-Absorption Edge of Hydrogenated Amorphous Silicon

TL;DR: The effect of thermal and structural disorder on the electronic structure of hydrogenated amorphous silicon is investigated by measurement of the shape of the optical absorption edge as a function of temperature and thermal evolution of hydrogen as discussed by the authors.
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