Journal ArticleDOI
Examination of Conditions under Which the Reduction of the Cobaltocenium Cation Can Be Used as a Standard Voltammetric Reference Process in Organic and Aqueous Solvents
R. S. Stojanovic,Alan M. Bond +1 more
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In this paper, the two one-electron proccesses for reduction of the cobaltocenlum cation as the hexafluorophosphate salt have been studied extensively in both aprotic and protic solvents at a hanging mercury drop electrode and at conventionally and microsized platinum, goid, and glassy carbon disk electrodes of various radii.Abstract:
The two one-electron proccesses for reduction of the cobaltocenlum cation as the hexafluorophosphate salt have been studied extensively in both aprotic and protic solvents at a hanging mercury drop electrode and at conventionally and microsized platinum, goid, and glassy carbon disk electrodes of various radii. Under carefully chosen conditions, both the Cc + /Cc 0 and Cc 0 /Cc - couples (Cc=cobaltocene) can be used as reversible voltammetric reference systemsread more
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A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage
TL;DR: This Review summarizes the design rationale, fundamentals and characterization of Li-redox flow batteries from a chemistry and material perspective, with particular emphasis on the new chemistries and materials.
Journal ArticleDOI
Voltammetry in Room Temperature Ionic Liquids: Comparisons and Contrasts with Conventional Electrochemical Solvents
Laura E. Barrosse-Antle,Alan M. Bond,Richard G. Compton,Aoife M. O'Mahony,Emma I. Rogers,Debbie S. Silvester +5 more
TL;DR: The recent literature is surveyed to explore the nature of voltammetry in room temperature ionic liquids and the extent of similarities with conventional electrochemical solvents is reported and some surprising differences are noted.
Journal ArticleDOI
Electrochemistry of Room Temperature Protic Ionic Liquids
Chuan Zhao,Geoffrey L. Burrell,Angel A. J. Torriero,Frances Separovic,Noel F. Dunlop,Douglas R. MacFarlane,Alan M. Bond +6 more
TL;DR: The survey highlights the problems with voltammetric studies in highly viscous room temperature protic ionic liquids and also suggests the way forward with respect to their possible industrial use.
Journal ArticleDOI
Improved Electrochemistry in Low-Polarity Media Using Tetrakis(pentafluorophenyl)borate Salts as Supporting Electrolytes.
TL;DR: The nichtkoordinierende Anion [NBu4][B(C6F5)4]− macht Kationen und Polykationen loslich und ermoglicht so die Bildung und Untersuchung solcher Systeme in Medien with niedriger Dielektrizitatskonstante.
Journal ArticleDOI
Practical considerations associated with voltammetric studies in room temperature ionic liquids
Jie Zhang,Alan M. Bond +1 more
TL;DR: Recent developments associated with voltammetric studies in ionic liquid media have been critically reviewed, as are limitations encountered by the presence of impurities and problems related to purification and recovery of ionic liquids.
References
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Journal ArticleDOI
Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983)
G. Gritzner,J. Kuta +1 more
TL;DR: In this article, the authors indique les procedes pour la mesure et le report des potentiels d'electrode dans des solvants non aqueux, vis-a-vis de ces systemes redox de reference.
Journal ArticleDOI
Ultrafast Voltammetry and Voltammetry in Highly Resistive Solutions with Microvoltammetric Electrodes
Jonathon O. Howell,R.M. Wightman +1 more
TL;DR: On peut realiser des etudes de voltammetrie cyclique en presence d'electrodes microvoltammetriques, a des vitesses de balayage tres rapides (jusqu'a 100 kVs −1 ) ou dans des solutions a forte resistivite par suite d'une chute ohmique reduite and de la capacite de the double couche as discussed by the authors.
Journal ArticleDOI
A comparison of the chronoamperometric response at inlaid and recessed disc microelectrodes
TL;DR: In this paper, the behavior of inlaid disc and recessed disc microelectrodes of identical radii under chronoamperometric conditions is compared both theoretically and experimentally.