Journal ArticleDOI
Facile Oxidation of Aldehydes to Acids and Esters with Oxone
TLDR
A highly efficient, mild, and simple protocol is presented for the oxidation of aldehydes to carboxylic acids utilizing Oxone as the sole oxidant.About:
This article is published in Organic Letters.The article was published on 2003-03-08. It has received 412 citations till now. The article focuses on the topics: Alcohol oxidation.read more
Citations
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Journal ArticleDOI
Advances in Homogeneous and Heterogeneous Catalytic Asymmetric Epoxidation
TL;DR: This paper presents results of aalysis experiment conducted at the Dalian Institute of Chemical Physics of Chinese Academy of Sciences (Dalian 116023) and Jingmen Technological College (Jingmen 448000) using gas chromatography for the recovery of Na6(CO3) from Na2SO4.
Journal ArticleDOI
Hypervalent iodine reagents as a new entrance to organocatalysts
Toshifumi Dohi,Yasuyuki Kita +1 more
TL;DR: The historical background and the efforts made to realize the catalytic utilization of hypervalent iodine reagents are highlighted, especially with focus on iodine(iii).
Journal ArticleDOI
Oxidation of Organic Compounds in Water by Unactivated Peroxymonosulfate
TL;DR: It is shown that PMS without explicit activation undergoes direct reaction with a variety of compounds, including antibiotics, pharmaceuticals, phenolics, and commonly used singlet-oxygen traps and quenchers, specifically furfuryl alcohol (FFA), azide, and histidine.
Journal ArticleDOI
Hypervalent iodine-mediated oxidation of alcohols
Muhammet Uyanik,Kazuaki Ishihara +1 more
TL;DR: The design of hypervalent iodine catalysts is focused on and the discovery and development of the oxidation of alcohols with the stoichiometric or catalytic use of hyperValent iodine compounds is reviewed.
Journal ArticleDOI
Liquid phase oxidation chemistry in continuous-flow microreactors
Hannes P. L. Gemoets,Yuanhai Su,Minjing Shang,Volker Hessel,Rafael Luque,Timothy Noël,Timothy Noël +6 more
TL;DR: An up-to-date overview of both technological and chemical aspects of liquid phase oxidation chemistry in continuous-flow microreactors is given, including the use of oxygen, hydrogen peroxide, ozone and other oxidants in flow.
References
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Journal ArticleDOI
New methods for the oxidation of aldehydes to carboxylic acids and esters
Journal ArticleDOI
100 Years of Baeyer–Villiger Oxidations
Michael Renz,Bernard Meunier +1 more
TL;DR: In this paper, the authors report the discovery of the formation of esters and lactones by oxidation of ketones with a peroxide derivative, namely the Baeyer-Villiger reaction.
Journal ArticleDOI
Chemoselective oxidation of sulfides to sulfones with potassium hydrogen persulfate
Barry M. Trost,Dennis P. Curran +1 more
TL;DR: Potassium hydrogen persulfate in aqueous methanol was found to be a convenient, inexpensive, and chemoselective reagent for the oxidation of sulfides to sulfones and sulfoxides in the presence of other common functional groups as mentioned in this paper.
Journal ArticleDOI
Osmium tetroxide-promoted catalytic oxidative cleavage of olefins: an organometallic ozonolysis.
TL;DR: A mild, organometallic alternative to ozonolysis utilizing oxone and OsO(4) is presented, which is a direct oxidation of olefins via the carbon-carbon cleavage of an osmate ester by the action of oxone.
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