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Journal ArticleDOI

Gold nanoshells improve single nanoparticle molecular sensors

TLDR
In this article, the authors focus on the narrow homogeneous line width of only 180 meV and show that the particle plasmon resonance responds more sensitively to changes in the environment, the biological spectral window is accessible and the scattering spectra show sharper resonances.
Abstract
Molecular sensors based on scattering spectroscopy of single gold nanoparticles can be improved three-fold by the use of gold nanoshells instead of solid gold nanoparticles. The particle plasmon resonance responds more sensitively to changes in the environment, the biological spectral window is accessible, and the scattering spectra show sharper resonances. In particular, we focus our discussion on the narrow homogeneous line width of only 180 meV.

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Citations
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Book

Plasmonics: Fundamentals and Applications

TL;DR: In this paper, the authors discuss the role of surface plasmon polaritons at metal/insulator interfaces and their application in the propagation of surfaceplasmon waveguides.
Journal ArticleDOI

Gold and Silver Nanoparticles in Sensing and Imaging: Sensitivity of Plasmon Response to Size, Shape, and Metal Composition

TL;DR: This work investigated the dependence of the sensitivity of the surface plasmon resonance response to changes in their surrounding environment and the relative contribution of optical scattering to the total extinction, on the size and shape of nanorods and the type of metal, that is, Au vs Ag.
Journal ArticleDOI

Bimetallic Nanocrystals: Syntheses, Properties, and Applications

TL;DR: A comprehensive review of recent research activities on bimetallic nanocrystals, featuring key examples from the literature that exemplify critical concepts and place a special emphasis on mechanistic understanding.
Journal ArticleDOI

Review of Some Interesting Surface Plasmon Resonance-enhanced Properties of Noble Metal Nanoparticles and Their Applications to Biosystems

TL;DR: In this article, a review of the plasmon resonance (SPR) enhanced optical properties of noble metal nanoparticles is presented, with an emphasis on the recent advances in the utility of these plasmoric properties in molecular-specific imaging and sensing, photo-diagnostics, and selective photothermal therapy.
References
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Journal ArticleDOI

Optical Constants of the Noble Metals

TL;DR: In this paper, the optical constants for the noble metals (copper, silver, and gold) from reflection and transmission measurements on vacuum-evaporated thin films at room temperature, in the spectral range 0.5-6.5 eV.
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Surface Plasmon Spectroscopy of Nanosized Metal Particles

TL;DR: In this paper, the use of optical measurements to monitor electrochemical changes on the surface of nanosized metal particles is discussed within the Drude model, and the absorption spectrum of a metal sol in water is shown to be strongly affected by cathodic or anodic polarization, chemisorption, metal adatom deposition, and alloying.
Journal ArticleDOI

A nanoscale optical biosensor: sensitivity and selectivity of an approach based on the localized surface plasmon resonance spectroscopy of triangular silver nanoparticles.

TL;DR: The LSPR nanobiosensor provides a pathway to ultrasensitive biodetection experiments with extremely simple, small, light, robust, low-cost instrumentation that will greatly facilitate field-portable environmental or point-of-service medical diagnostic applications.
Journal ArticleDOI

Single Silver Nanoparticles as Real-Time Optical Sensors with Zeptomole Sensitivity

TL;DR: In this article, the authors demonstrate the localized surface plasmon resonance λmax response of individual Ag nanoparticles to the formation of a monolayer of small-molecule adsorbates.
Journal ArticleDOI

Drastic reduction of plasmon damping in gold nanorods.

TL;DR: In this paper, the dephasing of particle plasmons was investigated using light-scattering spectroscopy on individual gold nanoparticles, and a drastic reduction of the plasmon de-phasing rate in nanorods as compared to small nanospheres due to a suppression of interband damping was found.
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