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Growing smooth epitaxial layers on misoriented substrates

TLDR
In this article, a process for improving the smoothness of semiconductor layers grown by epitaxy is described, which is achieved by misorienting the growth surface of the substrate from a major crystallographic plane by a small critical angle approximately equal to the tread-to-riser angle of terraces.
Abstract
A process for improving the smoothness of semiconductor layers grown by epitaxy is described. Smooth epitaxial layers, free of crystal terraces, are attained by misorienting the growth surface of the substrate from a major crystallographic plane by a small critical angle approximately equal to the tread-to-riser angle of terraces which would be formed if the epitaxial layer were deposited on a growth surface nominally parallel to the major plane. The critical angle is a function of both the growth temperature and the crystal composition. Specific examples for the growth of LPE Al x Ga 1-x As at various growth temperatures and values of x on GaAs substrates misoriented from the (100) and (111)B major planes are given. Also described are examples of silicon layers grown by CVD on (111) substrates to measure the critical angle in the (112) direction.

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References
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Method of crystallizing a binary semiconductor compound

TL;DR: In this article, a method of crystallizing a binary semiconductor compound from a liquid solution of the compound in one of its components, e.g. gallium arsenide in gallium, is presented.
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Epitaxial gallium arsenide

Abstract: 1. A study has been made of the growth of epitaxial gallium arsenide films on planes having simple and complicated crystallographic indices over the substrate-orientation range (111)A-(100)-(111)B. 2. The tangential velocity of an isolated growth step and the diffusion length for adsorbed atoms on the (111)A, (111)B, and (100) planes have been determined. 3. The anisotropy in the growth rates of epitaxial films on various planes has been calculated; comparison shows a satisfactory agreement with experiment.
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