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Journal ArticleDOI

Heterogeneous photocatalytic synthesis of ammonia from water and nitrogen

Hajime Miyama, +2 more
- 15 Sep 1980 - 
- Vol. 74, Iss: 3, pp 523-524
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TLDR
In this paper, a photocatalytic synthesis of ammonia from water and nitrogen was performed using binary wafered catalysts prepared with semiconductor powder (TiO2, SrTiO3, CdS or GaP).
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This article is published in Chemical Physics Letters.The article was published on 1980-09-15. It has received 113 citations till now. The article focuses on the topics: Platinum black & Ammonia.

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Citations
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Chemical structures and performance of perovskite oxides.

TL;DR: A detailed study of the structure of Perovskites and their properties in the context of a reducing Atmosphere andHydrogenation and Hydrogenolysis Reactions 2006 shows that the structure and properties of these minerals have changed little in the intervening years.
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Development of alternative photocatalysts to TiO2: Challenges and opportunities

TL;DR: In this article, the main achievements obtained with photocatalyst alternatives to TiO2 in the three main niches for this technology are summarized, with an historical perspective, in order to assess which of the photoactive materials are best for each particular application.
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Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction

TL;DR: It is demonstrated that illuminated hydrogen-terminated diamond yields facile electron emission into water, thus inducing reduction of N₂ to NH₃ at ambient temperature and pressure.
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Semiconductor Photocatalysis—Mechanistic and Synthetic Aspects

TL;DR: Novel atom-economic C-C and C-N coupling reactions illustrate the relevance of semiconductor photocatalysis for organic synthesis, and demonstrate that the multidisciplinary field combines classical photochemistry with electrochemistry, solid-state chemistry, and heterogeneous catalysis.
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Photocatalytic Conversion of Nitrogen to Ammonia with Water on Surface Oxygen Vacancies of Titanium Dioxide

TL;DR: It is reported that a commercially available TiO2 with a large number of surface oxygen vacancies, when photoirradiated by UV light in pure water with N2, successfully produces NH3.
References
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Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders

TL;DR: In this paper, the photoelectrocatalytic reduction of carbon dioxide to form organic compounds such as formic acid, formaldeyde, methyl alcohol and methane, in the presence of photosensitive semiconductor powders suspended in water as catalysts, is described.
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Photolysis of water and photoreduction of nitrogen on titanium dioxide

TL;DR: The photolysis of chemisorbed water on incompletely outgassed TiO/sub 2/ powder yields H 2 and O 2 in the molar ratio of 2 : 1 if conducted under argon in the presence of molecular nitrogen as mentioned in this paper.
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