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High performance perovskite solar cells by hybrid chemical vapor deposition

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TLDR
In this article, a perovskite solar cell using hybrid chemical vapor deposition (HCVD) has been demonstrated, achieving an efficiency of 11.8% with approximately 1100 h storage in dry N2 gas.
Abstract
Organometal halide based perovskites are promising materials for solar cell applications and are rapidly developing with current devices reaching ∼19% efficiency. In this work we introduce a new method of perovskite synthesis by hybrid chemical vapor deposition (HCVD), and demonstrate efficiencies as high as 11.8%. These cells were found to be stable with time, and retained almost the same efficiency after approximately 1100 h storage in dry N2 gas. This method is particularly attractive because of its ability to scale up to industrial levels and the ability to precisely control gas flow rate, temperature, and pressure with high reproducibility. This is the first demonstration of a perovskite solar cell using chemical vapor deposition and there is likely still room for significant optimization in efficiency.

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Journal ArticleDOI

Acceleration effect of chlorine in the gas-phase growth process of CH3NH3PbI3(Cl) films for efficient perovskite solar cells

TL;DR: In this paper, an NH4Cl-assisted chemical vapor deposition (CVD) method for fabricating efficient perovskite solar cells (PSCs) was reported, and the average power conversion efficiency was significantly enhanced from 10.86% to 12.2%.
Journal ArticleDOI

Influence of TiO2 Blocking Layer Morphology on Planar Heterojunction Perovskite Solar Cells

TL;DR: In this paper, the authors investigated the influence of the morphology, conductivity, and photoluminescence quenching abiliti cation on perovskite solar cells.
Patent

System and method based on low-pressure chemical vapor deposition for fabricating perovskite film

TL;DR: In this paper, a perovskite film fabrication method and a system including a housing for use as a CVD furnace having first and second sections coupled with first temperature control units, respectively.
Journal ArticleDOI

Perovskite solar cells by vapor deposition based and assisted methods

TL;DR: In this paper , the advances in vapor-based and assisted methods for the fabrication of perovskite solar cells are introduced, and the quality of the perovsite layers (i.e., morphology, crystallinity, defect chemistry, carrier lifetime) fabricated by different methods is compared.
References
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Journal ArticleDOI

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI

Sequential deposition as a route to high-performance perovskite-sensitized solar cells

TL;DR: A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Journal ArticleDOI

Efficient planar heterojunction perovskite solar cells by vapour deposition

TL;DR: It is shown that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.
Journal ArticleDOI

Interface engineering of highly efficient perovskite solar cells

TL;DR: Perovskite films received a boost in photovoltaic efficiency through controlled formation of charge-generating films and improved current transfer to the electrodes and low-temperature processing steps allowed the use of materials that draw current out of the perovskites layer more efficiently.
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Who invented perovskite solar cell?

This is the first demonstration of a perovskite solar cell using chemical vapor deposition and there is likely still room for significant optimization in efficiency.