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High performance perovskite solar cells by hybrid chemical vapor deposition

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In this article, a perovskite solar cell using hybrid chemical vapor deposition (HCVD) has been demonstrated, achieving an efficiency of 11.8% with approximately 1100 h storage in dry N2 gas.
Abstract
Organometal halide based perovskites are promising materials for solar cell applications and are rapidly developing with current devices reaching ∼19% efficiency. In this work we introduce a new method of perovskite synthesis by hybrid chemical vapor deposition (HCVD), and demonstrate efficiencies as high as 11.8%. These cells were found to be stable with time, and retained almost the same efficiency after approximately 1100 h storage in dry N2 gas. This method is particularly attractive because of its ability to scale up to industrial levels and the ability to precisely control gas flow rate, temperature, and pressure with high reproducibility. This is the first demonstration of a perovskite solar cell using chemical vapor deposition and there is likely still room for significant optimization in efficiency.

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Polymeric Dopant-Free Hole Transporting Materials for Perovskite Solar Cells: Structures and Concepts towards Better Performances.

TL;DR: In this review, all the dopant-free polymeric HTMs known so far in the perovskite solar cells field are collected, providing a brief historical introduction, followed by the classification and analysis of the polymeric structures, based on their building blocks, trying to find structure–activity relationships whenever possible.
Journal ArticleDOI

Surface-related properties of perovskite CH3NH3PbI3 thin films by aerosol-assisted chemical vapour deposition

TL;DR: In this paper, a modified three-step aerosol assisted chemical vapour deposition process was used to grow dense and uniform CH3NH3PbI3 thin films directly on borosilicate glass.
Journal ArticleDOI

Compact Layers of Hybrid Halide Perovskites Fabricated via the Aerosol Deposition Process—Uncoupling Material Synthesis and Layer Formation

TL;DR: The successful fabrication of CH3NH3PbI3 perovskite layers by the aerosol deposition method (ADM) allows for enhanced and easy control over the fabrication of perovSkite-based devices, further paving the way for their commercialization.
Journal ArticleDOI

CsPbBr3 quantum dots assisted crystallization of solution-processed perovskite films with preferential orientation for high performance perovskite solar cells

TL;DR: A feasible way to prepare high quality perovskite films for optoelectronic applications is demonstrated by employing CsPbBr3 QDs as an additive into diethyl ether anti-solvent for reduced defects and increased carrier lifetime.
Journal ArticleDOI

Construction of nanowire CH3NH3PbI3-based solar cells with 17.62% efficiency by solvent etching technique

TL;DR: In this paper, a CH 3 NH 3 PbI 3 -based solar cells device with nanowire film morphology and p-i-n structure was successfully constructed by solvent etching technique.
References
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Journal ArticleDOI

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI

Sequential deposition as a route to high-performance perovskite-sensitized solar cells

TL;DR: A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Journal ArticleDOI

Efficient planar heterojunction perovskite solar cells by vapour deposition

TL;DR: It is shown that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.
Journal ArticleDOI

Interface engineering of highly efficient perovskite solar cells

TL;DR: Perovskite films received a boost in photovoltaic efficiency through controlled formation of charge-generating films and improved current transfer to the electrodes and low-temperature processing steps allowed the use of materials that draw current out of the perovskites layer more efficiently.
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Who invented perovskite solar cell?

This is the first demonstration of a perovskite solar cell using chemical vapor deposition and there is likely still room for significant optimization in efficiency.