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High performance perovskite solar cells by hybrid chemical vapor deposition

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TLDR
In this article, a perovskite solar cell using hybrid chemical vapor deposition (HCVD) has been demonstrated, achieving an efficiency of 11.8% with approximately 1100 h storage in dry N2 gas.
Abstract
Organometal halide based perovskites are promising materials for solar cell applications and are rapidly developing with current devices reaching ∼19% efficiency. In this work we introduce a new method of perovskite synthesis by hybrid chemical vapor deposition (HCVD), and demonstrate efficiencies as high as 11.8%. These cells were found to be stable with time, and retained almost the same efficiency after approximately 1100 h storage in dry N2 gas. This method is particularly attractive because of its ability to scale up to industrial levels and the ability to precisely control gas flow rate, temperature, and pressure with high reproducibility. This is the first demonstration of a perovskite solar cell using chemical vapor deposition and there is likely still room for significant optimization in efficiency.

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Journal ArticleDOI

A cation-regulation strategy for achieving high-performance perovskite solar cells via a fully-evaporation process

TL;DR: In this paper, a CsMA-based perovskite film was prepared via a two-step evaporation process, and the power conversion efficiency (PCE) of the champion device is 17.15% (JSC = 22.59 mAh, VOC = 1.03 V, FF = 73.71%).
Proceedings ArticleDOI

Novel growth techniques for the deposition of high-quality perovskite thin films

TL;DR: In this paper, the authors investigated the growth of high quality CH3NH3PbI3 (MAPI) thin films using both vapor and solution techniques and showed that the hybrid chemical vapor deposition technique (HCVD) technique is well suited for the deposition of evenly distributed nucleation sites and the optimization of the crystallization rate of the film through detailed monitoring of the thermal profile of the growth process.
Patent

Preparation and application of TiO2-CH3NH3PbI3 photoelectric M2 macrophage sensor

TL;DR: In this paper, a photoelectric M2 macrophage sensor based on a TiO2-H3NH3PbI3 compound serving as a beacon substance is presented.
Proceedings ArticleDOI

Facile Synthesis of Bismuth-Based Perovskite and Solvent Engineering for Improving the Crystallinity of Lead-Free Perovskite Material: A Microstructural Exploration

TL;DR: In this article, bismuth-based perovskite thin film has been synthesized and the different solvent precursor in lead-free methyl ammoniumbismuth bromide (MABiBr3) was investigated.
References
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Journal ArticleDOI

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI

Sequential deposition as a route to high-performance perovskite-sensitized solar cells

TL;DR: A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Journal ArticleDOI

Efficient planar heterojunction perovskite solar cells by vapour deposition

TL;DR: It is shown that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.
Journal ArticleDOI

Interface engineering of highly efficient perovskite solar cells

TL;DR: Perovskite films received a boost in photovoltaic efficiency through controlled formation of charge-generating films and improved current transfer to the electrodes and low-temperature processing steps allowed the use of materials that draw current out of the perovskites layer more efficiently.
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Who invented perovskite solar cell?

This is the first demonstration of a perovskite solar cell using chemical vapor deposition and there is likely still room for significant optimization in efficiency.