Journal ArticleDOI
Homo- and heterometallic polynuclear transition metal catalysts for alkane CH bonds oxidative functionalization: Recent advances
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TLDR
In this article, the synthesis of homo-and heterometallic polynuclear complexes of 3D metals with N,O-donor ligands and their application in homogeneous catalytic alkane hydroxylation and hydrocarboxylation is discussed.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2018-01-15. It has received 106 citations till now. The article focuses on the topics: Coordination complex & Homogeneous catalysis.read more
Citations
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Hybrid materials for heterogeneous photocatalytic degradation of antibiotics
TL;DR: In this paper, the authors analyze and discuss the literature concerning the application of metal-based hybrid materials as heterogeneous photocatalysts for downstream depletion of antibiotics through advanced oxidation processes (AOP) using semiconductor photosensitization or photo-Fenton oxidation processes.
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Recent advances in heterometallic polyoxotitanium clusters
TL;DR: In this article, a review of the recent progress on metal ion doping in heterometallic polyoxotitanium clusters (HPTCs) is presented, and potential theoretical models for the rational design of photocatalysts and solar energy capture are provided.
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Recent progress on exploring µ-oxo bridged binuclear porphyrinoid complexes in catalysis and material science
TL;DR: In this article, a review covers recent advances in the preparation, characterization and application of µ-oxo dimeric complexes with different metals and non-metal and macrocyclic ligands achieved during last ten years.
Journal ArticleDOI
High-Cluster (Cu9) Cage Silsesquioxanes: Synthesis, Structure, and Catalytic Activity.
Grigorii S. Astakhov,Grigorii S. Astakhov,Alexey N. Bilyachenko,Alexey N. Bilyachenko,Alexander A. Korlyukov,Alexander A. Korlyukov,Mikhail M. Levitsky,Lidia S. Shul’pina,Xavier Bantreil,Frédéric Lamaty,Anna V. Vologzhanina,Elena S. Shubina,Pavel V. Dorovatovskii,Dmytro S. Nesterov,Armando J. L. Pombeiro,Georgiy B. Shul'pin,Georgiy B. Shul'pin +16 more
TL;DR: Catalytic studies of compound 1 demonstrated its high activity in hydroperoxidation of alkanes with H2O2 and oxidation of alcohols to ketones with tert-BuOOH and single-crystal X-ray diffraction studies showed the catalyst loading could be reduced down to 100 ppm of Cu.
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Hydrogen Peroxide and Metalloporphyrins in Oxidation Catalysis: Old Dogs with Some New Tricks
TL;DR: The use of metalloporphyrin analogues as biomimetic oxidation catalysts is an evolutionary topic of research as discussed by the authors, and the most important and illustrative examples for this period can be found in this paper.
References
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Magnetic bistability in a metal-ion cluster
TL;DR: In this article, it was shown that the magnetization of the Mn12 cluster is highly anisotropic and the magnetisation relaxation time becomes very long below a temperature of 4 K, giving rise to pronounced hysteresis.
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Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry
TL;DR: Electro-Fenton (EF) Process 6585 4.2.1.
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Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
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C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals
TL;DR: This Review provides an overview of C-H bond functionalization strategies for the rapid synthesis of biologically active compounds such as natural products and pharmaceutical targets.