Influence of Slag as Additive on Compressive Strength of Fly Ash-Based Geopolymer

TLDR: In this paper, slag was utilized as an additive for fly ash-based geopolymers in order to increase the compressive strength of the geopolymer, and the results showed that the addition of slag could generate amorphous products and accelerate the reaction rate of raw materials.

Abstract: Slag was utilized as an additive for fly ash-based geopolymers in this study. It was found that the incorporation of slag could significantly increase the compressive strength of the geopolymer. The compressive strength of geopolymer with 4.0% slag reached 50 and 70 MPa when cured for 14 days at 30 and 70°C , respectively. The mechanism of slag as additive on the enhancement of compressive strength of geopolymer was investigated using X-ray diffractometer (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and mercury intrusion porosimetry (MIP). The XRD and FTIR results showed that the addition of slag could generate more amorphous products and accelerate the reaction rate of raw materials. From XPS results, the decrease of binding energy and a broadening of peaks were observed for Si 2p , Al 2p , and O 1s elements due to the Ca2+ provided by slag. The decrease in binding energy was more favorable to zeolite formation. The results of MIP suggested that the 4% sl...