Journal ArticleDOI
Infrared Spectroscopic Study of the Matrix-Isolated Complexes of TiCl(4) with PH(3) and AsH(3).
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This article is published in Inorganic Chemistry.The article was published on 1996-06-19. It has received 9 citations till now. The article focuses on the topics: Matrix (mathematics).read more
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Titanium(IV) chloride, zirconium(IV) chloride or boron trichloride and phosphine-promoted Baylis–Hillman reaction of aldehydes with α,β-unsaturated ketone
TL;DR: In the Baylis-Hillman reaction of aldehydes with an α,β-unsaturated ketone, the chlorinated compound 1 was obtained as the major product using tributylphosphine as a Lewis base in the presence of titanium(IV) chloride, zirconium(IV), or boron trichloride in dichloromethane at <−20°C as mentioned in this paper.
Journal ArticleDOI
Reactions of Aluminum, Gallium, and Indium (M) Atoms with Phosphine: Generation and Characterization of the Species M·PH3, HMPH2, and H2MPH
TL;DR: All the molecules have been identified by their IR spectra, the assignments being attested by the effects of deuteration and also by comparison either with the vibrational properties anticipated by density functional theory (DFT) calculations or with those of known, related molecules.
Journal ArticleDOI
Compounds featuring a bond between a Group 13 (M) and a Group 15 element (N or P) and with the formulae HmMNHn and HmMPHn: structural aspects and bonding
TL;DR: In this paper, the properties of the observed or potential reaction products are discussed and compared with particular reference to structural and energetic differences according to whether E = N or P. All the molecules have been characterised structurally, energetically and vibrationally by Density Functional Theory (DFT) calculations.
Journal ArticleDOI
Low valent and would-be multiply bonded derivatives of the Group 13 metals Al, Ga and In revealed through matrix isolation
TL;DR: In this paper, the authors surveyed Group 13 metal chemistry in the light of recent matrix-isolation and quantum chemical studies, and the structure, energies and reactivities of the compounds were reviewed.
References
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Journal ArticleDOI
Evaluated Gas Phase Basicities and Proton Affinities of Molecules; Heats of Formation of Protonated Molecules
TL;DR: In this paper, the available data on gas phase basicities and proton affinities of molecules are compiled and evaluated, and tables giving the molecules ordered according to proton affinity and (2) according to empirical formula, sorted alphabetically are provided.
Journal ArticleDOI
Matrix Isolation Method for the Experimental Study of Unstable Species
Journal ArticleDOI
Chemical vapor deposition of titanium nitride at low temperatures
Sarah Kurtz,Roy G. Gordon +1 more
TL;DR: In this paper, a new method was proposed for making titanium nitride (TiN) films at substrate temperatures between about 400 and 700°C, which is versatile with growth rates of up to 0.1 μm s −1 possible.
Journal ArticleDOI
Kinetical Aspects of the LPCVD of Titanium Nitride from Titanium Tetrachloride and Ammonia
TL;DR: In this article, the authors studied the deposition rate and film properties as a function of the deposition temperature and the partial pressure of the reactant gases in a CVD reactor at a total deposition pressure of 20.0 Pa (150 mtorr).
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