Iodine chemistry in the +1 oxidation state. I. The electronic spectra of OI−, HOI, and H2OI+
Jean Paquette,Beverly L. Ford +1 more
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In this paper, the electronic spectra for the hypoiodite ion (OI−), HOI, and its conjugate acid (H2OI+) in aqueous media were reported.Abstract:
Electronic spectra are reported for the hypoiodite ion (OI−), hypoiodous acid (HOI), and its conjugate acid (H2OI+) in aqueous media. Iodine in the +1 oxidation state was produced by either of the ...read more
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High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols
TL;DR: It is reported that chiral ammonium hypoiodite salts catalyze highly chemo- and enantioselective oxidative cyclization of γ-(2-hydroxyphenyl)ketones to 2-acyl chromans bearing a quaternary stereocenter, which serve as productive synthetic intermediates for tocopherols.
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Molecular Iodine Catalyzed Cross-Dehydrogenative Coupling Reaction between Two sp3 C–H Bonds Using Hydrogen Peroxide
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Mechanisms in Iodine Catalysis.
TL;DR: The experimental basis for the proposed modes of activation for iodine catalysis is summarized and typical iodine-catalyzed reactions are analyzed to gain more insights into the underlying reaction mechanisms.
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Hypoiodous acid: kinetics of the buffer-catalyzed disproportionation
TL;DR: In this article, the acid dissociation constant (pK(a)) of hypoiodous acid (HOI) has been determined spectrophotometrically as 10.4 +/- 0.1 (T = 25 degrees C; I = 50 mM).