Journal ArticleDOI
IR spectroscopy in catalysis
TLDR
In this paper, a review of the most popular IR spectroscopy applications for catalytic applications is presented, starting from the very general basis of the spectroscopic method applied and focusing on the adsorption of chelating compounds on surfaces of mineral oxides.About:
This article is published in Catalysis Today.The article was published on 2001-07-30. It has received 433 citations till now.read more
Citations
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Journal ArticleDOI
Superoxide Ion: Generation and Chemical Implications
TL;DR: This review comprises the main characteristics of O2(•-) followed by generation methods, and its potential applications including the destruction of hazardous chemicals, synthesis of organic compounds, and many other applications are highlighted.
Journal ArticleDOI
Catalysis by Supported Single Metal Atoms
TL;DR: In this article, the authors discuss the most recent advances in preparing, characterizing, and catalytically testing SACs with a focus on correlating the structural perspective of the anchored single metal atoms to the observed catalytic performances.
Journal ArticleDOI
Nanostructured oxides in chemistry: characterization and properties.
Marcos Fernández-García,Arturo Martínez-Arias,Jonathan C. Hanson,José Antonio Lozano Rodríguez +3 more
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FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide.
TL;DR: The decrease of HBI, the easy removal of DMAc, and the band at 1593cm(-1) supported the introduction of new chemical structure in cellulose.
References
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Journal ArticleDOI
Polarization characteristics from SFG spectra of clean and regulatively oxidized Ni(100) surfaces adsorbed by propionate and formate
Tetsuo Yuzawa,Tatsutoshi Shioda,Jun Kubota,Ken Onda,Akihide Wada,Kazunari Domen,Chiaki Hirose +6 more
TL;DR: In this article, the polarization characteristics of infrared-visible sum frequency generation (SFG) signals of molecules on metallic surfaces are different from those due to molecules on insulating surfaces.
Journal ArticleDOI
Site blocking effects in ethylidyne decomposition kinetics on Ru(001) : in-situ-study with infrared reflection absorption spectroscopy at elevated pressure
TL;DR: In this article, the authors investigated the decomposition kinetics of ethylidyne in the presence of coadsorbates on Ru(001) and showed that the stabilizing effect of CO and hydrogen is significantly enhanced at elevated pressure, supporting a model wherein an empty neighboring metal site is required before decomposition can proceed.
Journal ArticleDOI
Efficient direct synthesis of 2-ethylhexanal from n-butyraldehyde and hydrogen using palladium modified base catalysts
TL;DR: In this paper, a one-step synthesis of 2-ethylhexanal (2EH) from n-butyraldehyde and hydrogen gas has been studied over palladium modified base catalysts at 1-atm and 130-200°C by using a fixed-bed, integral-flow reactor.
Journal ArticleDOI
Catalytic monoepoxidation of butadiene over titanium silicate molecular sieves TS-1
TL;DR: Titanium silicate molecular sieves TS•1 have been prepared under hydrothermal conditions with tetrapropylammonium hydroxide as structure-directing agent.
Journal ArticleDOI
Characterization of AlPO systems, precursors of the novel basic catalyst family AlPON
J. J. Ben⩼ez,Miguel Ángel Centeno,José Antonio Odriozola,Roland Conanec,Roger Marchand,Yves Laurent +5 more
TL;DR: In this article, a spinel-like solid is proposed to alter the electronic density of oxide ions and phosphorus cations and hence their Lewis acid-base properties with respect to the amorphous solid having aluminium and phosphorus only in tetrahedral arrangement.