Journal ArticleDOI
Metal-Catalyzed Epoxidations of Alkenes with Hydrogen Peroxide
Benjamin S. Lane,Kevin Burgess +1 more
TLDR
Metal Oxides Generated in Situ 2461 4.1.Abstract:
3. Soluble Metal Oxides 2459 3.1. Polyoxometalates 2459 3.2. Peroxotungstates 2459 3.3. Peroxomolybdates 2460 3.4. Methyltrioxorhenium 2461 3.5. Other Metal Oxides 2461 4. Metal Oxides Generated in Situ 2461 4.1. Selenium and Arsenic Compounds 2461 4.2. Simple Metal Salts 2462 5. Coordination Complexes 2463 5.1. Manganese Porphyrins 2463 5.2. Iron Porphyrins 2464 5.3. Manganese Salen Complexes 2466 5.4. 1,4,7-Triazacyclononane (TACN) Complexes 2466 5.5. Iron and Manganese Pyridyl-Amine Complexes 2468read more
Citations
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Journal ArticleDOI
Hydrogen Peroxide Synthesis: An Outlook beyond the Anthraquinone Process
TL;DR: The direct synthesis of H 2O2 from O2 and H2 using a variety of catalysts, and the factors influencing the formation and decomposition of H2O2 are examined in detail in this Review.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
Journal ArticleDOI
Biologically inspired oxidation catalysis
Lawrence Que,William B. Tolman +1 more
TL;DR: The development of processes for selective hydrocarbon oxidation is a goal that has long been pursued, and extensive studies have revealed the key chemical principles that underlie their efficacy as catalysts for aerobic oxidations.
Journal ArticleDOI
Biobased thermosetting epoxy: present and future.
Rémi Auvergne,Sylvain Caillol,Ghislain David,Bernard Boutevin,Jean-Pierre Pascault,Jean-Pierre Pascault +5 more
TL;DR: This paper aims to provide a history of the use of glass in the construction of buildings in Montpellier and its applications in the 21st Century.
References
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Journal ArticleDOI
Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts
TL;DR: In this paper, the authors dealt with enantioselective one oxygen atom transfer reactions (epoxidation, oxidation of enolates, and oxidation of sulphide to sulphoxides) catlaysed by optically active (salen)manganese(III)complexes.
Book
Metal-catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic Methodology Including Biochemical Processes
Roger A. Sheldon,Jay K. Kochi +1 more
Journal ArticleDOI
Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite
TL;DR: In this article, the epoxidation of propylene with hydrogen peroxide in the liquid phase, in the presence of titanium silicalite catalyst (TS-1), is described.