Journal ArticleDOI
Metal‐Free Oxidative Carbon‐Heteroatom Bond Formation Through C–H Bond Functionalization
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TLDR
In this paper, the development of metal-free coupling methods for unactivated compounds under oxidative reaction conditions is discussed with numerous examples. And the utility of these methods in syntheses of desired products and the mechanisms of their formation are discussed.About:
This article is published in European Journal of Organic Chemistry.The article was published on 2013-09-01. It has received 243 citations till now. The article focuses on the topics: Heteroatom.read more
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Advances in Synthetic Applications of Hypervalent Iodine Compounds
TL;DR: One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.
Journal ArticleDOI
Electrochemical strategies for C-H functionalization and C-N bond formation.
TL;DR: This review provides an overview on the use of anodic electrochemical methods for expediting the development of carbon-hydrogen functionalization and carbon-nitrogen bond formation strategies and aims to provide inspiration for future synthetic applications in the field of electrosynthesis.
Journal ArticleDOI
Organocatalysis in Inert C–H Bond Functionalization
Yan Qin,Lihui Zhu,Sanzhong Luo +2 more
TL;DR: This review provides a comprehensive summary of organocatalysis in inert C-H bond functionalization over the past two decades as well as those activated benzylic, allylic, and C- H bonds alpha to the heteroatom such as nitrogen and oxygen.
Journal ArticleDOI
An Iodine-Catalyzed Hofmann–Löffler Reaction†
Claudio Martínez,Kilian Muñiz +1 more
TL;DR: An attractive iodine oxidation catalysis is shown to promote the convenient conversion of carbon-hydrogen bonds into carbon-nitrogen bonds with unprecedented complete selectivity.
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Iodine‐Catalyzed Oxidative Coupling Reactions Utilizing C ? H and X ? H as Nucleophiles
Dong Liu,Aiwen Lei,Aiwen Lei +2 more
TL;DR: A brief summary of recent development on iodine-catalyzed oxidative coupling reactions utilizing C - H and X - H as nucleophiles is given.
References
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Journal ArticleDOI
Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.
TL;DR: A number of improvements have developed the former process into an industrially very useful and attractive method for the construction of aryl -aryl bonds, but the need still exists for more efficient routes whereby the same outcome is accomplished, but with reduced waste and in fewer steps.
Journal ArticleDOI
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
TL;DR: Alkylations with Phenols, Nitrogen Nucleophiles in AAA Total Synthesis, and Considerations for Enantioselective Allylic Alkylation are presented.
Journal ArticleDOI
C-H Bond Functionalization in Complex Organic Synthesis
Kamil Godula,Dalibor Sames +1 more
TL;DR: In this paper, the functionalization of C-H bonds in complex organic substrates catalyzed by transition metal catalysts is studied and the key concepts and approaches aimed at achieving selectivity in complex settings are discussed.
Journal ArticleDOI
Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions
TL;DR: Oxidative X-X Bond Formations between Two Nucleophiles 1819 5.1.
C-H bond functionalization in complex organic synthesis
TL;DR: This work outlines the key concepts and approaches aimed at achieving selectivity in complex settings and discusses the impact these reactions have on synthetic planning and strategy in organic synthesis.
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