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Journal ArticleDOI

Metal-metal multiple bonds. 5. Molecular structure and fluxional behavior of tetraethylammonium μ -cyano-bis(cyclopentadienyldicarbonylmolybdate)(Mo-Mo) and the question of semibridging carbonyls.

M. David Curtis, +2 more
- 01 Jul 1980 - 
- Vol. 11, Iss: 41, pp 2096-2101
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This article is published in Inorganic Chemistry.The article was published on 1980-07-01. It has received 90 citations till now. The article focuses on the topics: Molecule & Tetraethylammonium.

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Journal ArticleDOI

A Heterobimetallic Mechanism for C–H Borylation Elucidated from Experimental and Computational Data

TL;DR: In this article, a complete mechanistic pathway for C-H borylation with Cu-Fe catalysts was proposed, which is consistent with experimental observations as well as first-principles quantum chemistry.
Journal ArticleDOI

Synthesis and characterization of heterobimetallic complexes with direct Cu-M bonds (M = Cr, Mn, Co, Mo, Ru, W) supported by N-heterocyclic carbene ligands: a toolkit for catalytic reaction discovery.

TL;DR: A series of (NHC)Cu-[M] complexes were synthesized via the addition of Na(+)[M](-) reagents to (N HC)CuCl synthons, allowing for controlled variation of nucleophile/electrophile pairing in the heterobimetallic species.
Book ChapterDOI

Unsaturated Dimetal Cyclopentadienyl Carbonyl Complexes

TL;DR: In this paper, the Cp* ligand is compared to the C5H4Me ligand, and it is shown that the C p' species is often higher than that of Cp compounds, while the chemistry is generally unaffected by the single methyl substituent.
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