The miniaturization of analytical instruments and packaging of novel sensors is an area that has attracted significant research interest and offers many opportunities for product commercialization. Electrochemical sensors have been used to detect a wide variety of compounds including toxic gases. A miniature electrochemical cell has been designed, constructed, and tested for functionality. The cell will be used in identifying and selecting chemical species in solutions. The cell was constructed of low temperature co-fired ceramic (LTCC) material using gold for the electrodes. Tests performed in sulfuric acid and sea water solutions show that the cell is functioning based on cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analysis. Miniaturization allows the cell to be deployed as a sensor in many different environments.

A number of emerging applications of low-temperature co-fired ceramic (LTCC) require embedded fluidic structure within the co-fired ceramic and or precise external dimensional tolerances. These structures enable the control of fluids for cooling, sensing, and biomedical applications, and variations in their geometry from the design can have a significant impact on the overall performance of the devices. One example of this type of application is a multilayer cooler developed recently by the authors for cooling laser diode bars. In many laser systems, laser diodes are the primary emitters, or assemblies of these diode bars are used to pump traditional laser crystals such as Nd:YLF. Assemblies of these diodes require large amounts of electrical current for proper operation, and the device operating temperature must be carefully controlled in order to avoid a shift in the output wavelength. These diodes are packaged into water-cooled assemblies and by their nature dissipate enormous amounts of heat, with waste heat fluxes on the order of 2000 W/cm2. The traditional solution to this problem has been the development of copper multilayer coolers. Assemblies of laser diodes are then formed by stacking these diode bars and coolers. Several problems exist with this approach including the erosion of the copper coolers by the coolant, a requirement for the use of deionized water within the system, and a significant CTE mismatch between the diode bar and the metal cooler. Diodes are bonded to these metal structures and liquid coolant is circulated through the metal layers in order to cool the diode bar. In contrast, the coolers developed by the authors utilize fluid channels and jets formed within LTCC as well as embedded cavity structures to control the flow of a high-velocity liquid and actively cool the laser diode bars mounted on the surface of the LTCC.† The dimensional tolerances of these cooler assemblies and complex shapes that are used to control the fluid can have a significant impact on the overall performance of the laser system. This paper describes the fabrication process used to create the precise channel and jet structures used in these LTCC-based coolers, as well as some of the challenges associated with these processes.

Miniature Multi-Electrode Electrochemical Cell in LTCC

Citations

Fabrication of Precise Fluidic Structures in LTCC

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