Book ChapterDOI
Mixed Valence Complexes of d5‐d6 Metal Centers
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This article is published in Progress in Inorganic Chemistry.The article was published on 2007-03-09. It has received 599 citations till now. The article focuses on the topics: Metal K-edge & Valence (chemistry).read more
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Electron transfers in chemistry and biology
Rudolph A. Marcus,Norman Sutin +1 more
TL;DR: In this paper, the electron transfer reactions between ions and molecules in solution have been the subject of considerable experimental study during the past three decades, including charge transfer, photoelectric emission spectra, chemiluminescent electron transfer, and electron transfer through frozen media.
Journal ArticleDOI
Electrically Conductive Metal-Organic Frameworks.
TL;DR: This Review discusses the efforts undertaken so far to achieve efficient charge transport in MOFs and focuses on four common strategies that have been harnessed toward high conductivities.
Journal ArticleDOI
Playing with organic radicals as building blocks for functional molecular materials
Imma Ratera,Jaume Veciana +1 more
TL;DR: This critical review provides an up-to-date survey to this new generation of multifunctional magnetic materials showing promise for applications in spintronics as well as bistable memory devices and sensing materials.
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Organometallic molecular wires and other nanoscale-sized devices: An approach using the organoiron (dppe)Cp*Fe building block
Frédéric Paul,Claude Lapinte +1 more
TL;DR: In this article, the potential that organometallic architectures consisting of two transition metal centers linked by an organic unsaturated spacer present for the study and development of new molecular wires is discussed.
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Manifestations of noninnocent ligand behavior.
TL;DR: The relationships of noninnocent ligand behavior with excited-state descriptions and perspectives regarding material properties and single-electron or multielectron reactivity are illustrated briefly.
References
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Journal ArticleDOI
Chemical and Electrochemical Electron-Transfer Theory
TL;DR: In this article, a review of electron transfer reactions is presented, focusing on the absence of bond rupture in the reaction step, which is a unique feature of purely electron-transfer reactions.
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On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions
TL;DR: A unified theory of homogeneous and electrochemical electron transfer rates using statistical mechanics is developed in this article, where the atomic motions inside the inner coordination shell of each reactant are treated as vibrations and the motions outside are treated by the particle description.
Book ChapterDOI
Mixed Valence Chemistry-A Survey and Classification
Melvin B. Robin,Peter Day +1 more
TL;DR: In this article, a review is concerned with the neglected class of inorganic compounds, which contain ions of the same element in two different formal states of oxidation, and a number of references cite that many individual examples of this class have been studied, yet they have very rarely been treated as a class, and there has never before, to our knowledge, been a systematic attempt to classify their properties in terms of their electronic and molecular structures.
Journal ArticleDOI
Homogeneous and heterogeneous optical and thermal electron transfer
TL;DR: In this article, a unified theory of optical and thermal outer-sphere electron transfer processes is outlined, in which the equations are obtained as special cases of general expressions for radiative and radiationless transition probabilities.