Electrically Conductive Metal-Organic Frameworks.
TLDR
This Review discusses the efforts undertaken so far to achieve efficient charge transport in MOFs and focuses on four common strategies that have been harnessed toward high conductivities.Abstract:
Metal–organic frameworks (MOFs) are intrinsically porous extended solids formed by coordination bonding between organic ligands and metal ions or clusters. High electrical conductivity is rare in M...read more
Citations
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Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications.
TL;DR: In this article, the authors provide an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.
Journal ArticleDOI
The Current Status of MOF and COF Applications
Ralph Freund,Orysia Zaremba,Giel Arnauts,Rob Ameloot,Grigorii Skorupskii,Mircea Dincă,Anastasiya Bavykina,Jorge Gascon,Aleksander Ejsmont,Joanna Gościańska,Markus Kalmutzki,Ulrich Lächelt,Evelyn Ploetz,Christian Diercks,Stefan Wuttke +14 more
TL;DR: The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties.
Prediction of a Two-Dimensional Organic Topological Insulator
TL;DR: This work identifies a recently experimentally made 2D organometallic framework, consisting of π-conjugated nickel-bis-dithiolene with a chemical formula Ni3C12S12, which exhibits nontrivial topological states in both a Dirac band and a flat band, therefore confirming the existence of OTI.
Journal ArticleDOI
Rare-Earth Doping in Nanostructured Inorganic Materials.
TL;DR: This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material.
Journal ArticleDOI
Highly Conductive Two-Dimensional Metal-Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability
Zhenzhen Wu,Zhenzhen Wu,David Adekoya,Xing Huang,Milton J. Kiefel,Jian Xie,Jian Xie,Wei Xu,Qichun Zhang,Qichun Zhang,Daoben Zhu,Shanqing Zhang +11 more
TL;DR: This work synthesized a robust and redox-active 2D metal-organic Frameworks (MOFs) [Cu3(C6S6)]n, namely Cu-BHT, which has a highly conjugated structure, affording a high electronic conductivity and would provide a practical strategy for the development of high-power energy storage materials.
References
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Journal ArticleDOI
Electric Field Effect in Atomically Thin Carbon Films
Kostya S. Novoselov,Andre K. Geim,Sergey V. Morozov,Da Jiang,Y. Zhang,S. V. Dubonos,Irina V. Grigorieva,A. A. Firsov +7 more
TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
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The electronic properties of graphene
TL;DR: In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.
Journal ArticleDOI
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.
TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Book
Electronic processes in non-crystalline materials
TL;DR: The Fermi Glass and the Anderson Transition as discussed by the authorsermi glass and Anderson transition have been studied in the context of non-crystalline Semiconductors, such as tetrahedrally-bonded semiconductors.