Journal ArticleDOI
N,N-dimethylformamide: a multipurpose building block.
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TLDR
Recent developments in the employment of DMF in the fields of formylation, aminocarbonylation, amination, amidation, and cyanation, as well as its reaction with arynes are summarized.Abstract:
Often used as a common solvent for chemical reations and utilized widely in industry as a reagent, N,N-dimethylformamide (DMF) has played an important role in organic synthesis for a long time. Numerous highly useful articles and reviews discussing its utilizations have been published. With a focus on the performance of DMF as a multipurpose precursor for various units in numerous reactions, this Minireview summarizes recent developments in the employment of DMF in the fields of formylation, aminocarbonylation, amination, amidation, and cyanation, as well as its reaction with arynes.read more
Citations
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Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives
TL;DR: In this article, the authors summarize the recent results devoted to the formation of nitrogen compounds obtained by reductive functionalization of CO2 in the presence of amines and discuss the opportunities and challenges facing the practical use of CO 2 in the production of nitrogen-containing molecules.
Journal ArticleDOI
Cobalt-catalyzed C-H cyanation of arenes and heteroarenes.
Jie Li,Lutz Ackermann +1 more
TL;DR: An in-situ generated cationic cobalt complex was identified as a versatile catalyst for the site-selective synthesis of various aromatic and heteroaromatic nitriles with ample substrate scope.
Journal ArticleDOI
Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂.
TL;DR: Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N-dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost-effective process.
Journal ArticleDOI
Direct approaches to nitriles via highly efficient nitrogenation strategy through C-H or C-C bond cleavage.
Teng Wang,Ning Jiao +1 more
TL;DR: In this Account, the direct nitrile synthesis methodologies have potential applications in the synthesis of biologically active molecules and drug candidates and explored environmentally friendly oxidants, such as molecular oxygen, to make the synthetic strategy more attractive.
Journal ArticleDOI
Rhodium-catalyzed directed C-H cyanation of arenes with N-cyano-N-phenyl-p-toluenesulfonamide.
TL;DR: A Rh-catalyzed directed C-H cyanation reaction was developed for the first time as a practical method for the synthesis of aromatic nitriles and tolerates a variety of synthetically important functional groups.
References
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Journal ArticleDOI
Synthesis of Silver Nanoprisms in DMF
TL;DR: In this article, a mixture of nanoprisms and nanospheroids was synthesized by boiling AgNO3 in N,N-dimethyl formamide, in the presence of poly(vinylpyrrolidone).
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Radical reactions of arenediazonium ions: An easy entry into the chemistry of the aryl radical
Journal ArticleDOI
Transformations of Chloroarenes, Catalyzed by Transition-Metal Complexes
Vladimir V. Grushin,Howard Alper +1 more
Journal ArticleDOI
Designer magnets containing cyanides and nitriles.
Joel S. Miller,Jamie L. Manson +1 more
TL;DR: Three-dimensional network solids exhibiting magnetic ordering have been made from several first-row metal ions and bridging unsaturated cyanide, tricyanomethanide, and/or dicyanamide ligands, which possess several different structural motifs, and the shorter the bridge, the stronger the interaction.
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