Journal ArticleDOI
Nanoscale polyoxometalate‐based inorganic/organic hybrids
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TLDR
The latest advances in the area of polyoxometalate (POM)-based inorganic/organic hybrid materials prepared by self-assembly, covalent modification, and supramolecular interactions are presented.Abstract:
The latest advances in the area of polyoxometalate (POM)-based inorganic/organic hybrid materials prepared by self-assembly, covalent modification, and supramolecular interactions are presented. This Review is composed of five sections and documents the effect of organic cations on the formation of novel POMs, surfactant encapsulated POM-based hybrids, polymeric POM/organic hybrid materials, POMs-containing ionic crystals, and covalently functionalized POMs. In addition to their role in the charge-balancing, of anionic POMs, the crucial role of organic cations in the formation and functionalization of POM-based hybrid materials is discussed.read more
Citations
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Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications
TL;DR: This review article provides an overview on the state of the art in POM post-functionalization and highlights the key design and structural features that permit the discovery of new hybrid-POM platforms to make the subject more comprehensible.
Journal ArticleDOI
Covalent multi-component systems of polyoxometalates and metal complexes: Toward multi-functional organic–inorganic hybrids in molecular and material sciences
Marie-Pierre Santoni,Marie-Pierre Santoni,Marie-Pierre Santoni,Garry S. Hanan,Bernold Hasenknopf,Bernold Hasenknopf +5 more
TL;DR: In this paper, the synthesis and characterization of both molecular and polymeric hybrids are discussed, and their potential applications in catalysis, material science and energy-related sciences are discussed.
Journal ArticleDOI
Polyoxometalate-based molecular/nano composites: Advances in environmental remediation by photocatalysis and biomimetic approaches to solar energy conversion
TL;DR: In this paper, the development of various molecular and nano composites derived from polyoxometalates (POMs) are discussed with regard to photocatalytic environmental remediation, hydrogen production, carbon dioxide reduction and photoelectrochemical solar cells.
Journal ArticleDOI
Covalently Tethered Polyoxometalate–Pyrene Hybrids for Noncovalent Sidewall Functionalization of Single‐Walled Carbon Nanotubes as High‐Performance Anode Material
TL;DR: In this paper, a covalently tethered polyoxometalate (POM) and pyrene hybrid (Py-SiW11) was used for the noncovalent functionalization of single-walled carbon nanotubes (SWNTs).
Journal ArticleDOI
Effective Synergistic Effect of Dipeptide-Polyoxometalate-Graphene Oxide Ternary Hybrid Materials on Peroxidase-like Mimics with Enhanced Performance.
TL;DR: The present method opens up a promising route in constructing heterogeneous peroxidase-like mimics through the use of POMs via the introduction of GO for building H2O2 sensors.
References
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Journal ArticleDOI
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
Michael T. Pope,Achim Müller +1 more
TL;DR: Inorganic metal-oxygen cluster anions form a class of compounds that is unique in its topological and electronic versatility and is important in several disciplines, such as analytical and clinical chemistry, catalysis (including photocatalysis), biochemistry, and medicine (antitumoral, antiviral, and even anti-HIV activity) as mentioned in this paper.
Journal ArticleDOI
Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices
TL;DR: In this critical review the synthetic and design approaches to the many polyoxometalate cluster types are presented encompassing all the sub-types of polyxometalates including, isopolyoxometAlates, heteropolyoxometricalates, and reduced molybdenum blue systems.
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Polyoxometalates: Building Blocks for Functional Nanoscale Systems
TL;DR: The possibilities of creating highly sophisticated functional hierarchical systems with multiple, interdependent, functionalities along with a critical analysis that allows the non-specialist to learn the salient features of POMs are discussed.
Journal ArticleDOI
Electronically Configurable Molecular-Based Logic Gates
C. P. Collier,Eric W. Wong,M. Belohradský,Françisco M. Raymo,J. F. Stoddart,Philip J. Kuekes,R. S. Williams,James R. Heath +7 more
TL;DR: Logic gates were fabricated from an array of configurable switches, each consisting of a monolayer of redox-active rotaxanes sandwiched between metal electrodes, which provided a significant enhancement over that expected for wired-logic gates.