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Nickel-Based Superalloys for Advanced Turbine Engines: Chemistry, Microstructure and Properties

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TLDR
The chemical, physical, and mechanical characteristics of nickel-based superalloys are reviewed with emphasis on the use of this class of materials within turbine engines as mentioned in this paper, and the role of major and minor alloying additions in multicomponent commercial cast and wrought super-alloys is discussed.
Abstract
The chemical, physical, and mechanical characteristics of nickel-based superalloys are reviewed with emphasis on the use of this class of materials within turbine engines. The role of major and minor alloying additions in multicomponent commercial cast and wrought superalloys is discussed. Microstructural stability and phases observed during processing and in subsequent elevated-temperature service are summarized. Processing paths and recent advances in processing are addressed. Mechanical properties and deformation mechanisms are reviewed, including tensile properties, creep, fatigue, and cyclic crack growth. I. Introduction N ICKEL-BASED superalloys are an unusual class of metallic materials with an exceptional combination of hightemperature strength, toughness, and resistance to degradation in corrosive or oxidizing environments. These materials are widely used in aircraft and power-generation turbines, rocket engines, and other challenging environments, including nuclear power and chemical processing plants. Intensive alloy and process development activities during the past few decades have resulted in alloys that can tolerate average temperatures of 1050 ◦ C with occasional excursions (or local hot spots near airfoil tips) to temperatures as high as 1200 ◦ C, 1 which is approximately 90% of the melting point of the material. The underlying aspects of microstructure and composition that result in these exceptional properties are briefly reviewed here. Major classes of superalloys that are utilized in gas-turbine engines and the corresponding processes for their production are outlined along with characteristic mechanical and physical properties.

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Journal ArticleDOI

VHCF life evolution after microstructure degradation of a Ni-based single crystal superalloy

TL;DR: In this paper, Ni-based single crystal superalloy (CMSX-4) has been studied at 20 kHz and temperature of 1000°C between 10 6 and 10 10 cycles.
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Electrochemical Dissolution Behavior of the Nickel-Based Cast Superalloy K423A in NaNO3 Solution

TL;DR: In this paper, the microstructure of the cast superalloy K423A was examined and numerous carbides were found to be distributed irregularly throughout the matrix, especially at the grain boundaries.
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Mechanism of heat affected zone cracking in Ni-based superalloy DZ125L fabricated by laser 3D printing technique

TL;DR: In this article, the authors studied the element, phase, defect, and strain distribution around an intergranular crack that initiated from the primary heat affected zone (HAZ) and provided a useful guideline for the optimization of the 3D printing process to repair Ni-based superalloys with high susceptibility to hot cracking.
Journal ArticleDOI

Structure and high temperature mechanical properties of novel non-equiatomic Fe-(Co, Mn)-Cr-Ni-Al-(Ti) high entropy alloys

TL;DR: In this article, four non-equiatomic Fe-(Co, Mn)-Cr-Ni-Al-(Ti) high entropy alloys, namely Fe36Mn21Cr18Ni15Al10, Fe36Co21Cr 18Ni 15Al10 and Fe35Mn20Cr17Ni12Al12Ti4, were produced by arc melting and a good correlation between the average valence electron concentration (VEC) value and the amount of the fcc phase was found.
Journal ArticleDOI

Fatigue crack growth mechanisms in powder metallurgy Ni-based superalloys—A review

TL;DR: In this article, a review of the mechanisms controlled by microstructural features including grain size, grain misorientation, γ′ size and distribution on short and long FCG behavior in PM Ni-based superalloys is discussed.
References
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Book

Dislocations in solids

TL;DR: In this article, Bertotti, Ferro, and Mazetti proposed a theory of dislocation drag in covalent crystals and formed a model of the formation and evolution of dislocations during irradiation.
Journal ArticleDOI

Creep resistance of CMSX-3 nickel base superalloy single crystals

TL;DR: In this paper, the authors studied the effect of dislocation-free nickel base superalloy single crystals with high volume fractions of the γ′ phase on their deformation and found that the dislocation free precipitates are resistant to shearing by dislocations.
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The precipitation of topologically close-packed phases in rhenium-containing superalloys

TL;DR: In this paper, the formation of topologically close-packed (TCP) phases due to the addition of solid solution strengtheners, such as rhenium, molybdenum and tungsten, has been studied.
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Dynamic recrystallization in nickel and nickel-iron alloys during high temperature deformation

TL;DR: In this paper, it is established from metallographic and flow stress observations that dynamic recrystallization occurs at strains greater than a critical value and results in a recrystized grain size which is determined entirely by the flow stress.
Journal ArticleDOI

Creep behaviour of Ni-base single-crystal superalloys with various γ' volume fraction

TL;DR: In this article, a third generation Ni-base single-crystal superalloy TMS-75 and its γ/γ " tie line alloys were designed to contain various volume fractions of γ, while the compositions of two individual phases were kept the same.