Journal ArticleDOI
Novel catalytic bromolactonization of alkenoic acids using iodobenzene and Oxone
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TLDR
In this paper, a catalytic reaction for bromolactonization of alkenoic acids was reported, where iodobenzene was used as recyclable catalyst in combination with Oxone® as terminal oxidant.About:
This article is published in Journal of Heterocyclic Chemistry.The article was published on 2011-05-01. It has received 17 citations till now. The article focuses on the topics: Iodobenzene & Sodium bromide.read more
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Advances in Synthetic Applications of Hypervalent Iodine Compounds
TL;DR: One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.
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Journey describing applications of oxone in synthetic chemistry
TL;DR: This paper presents a probabilistic analysis of the response of nanoporous materials to high-performance liquid chromatography and shows clear trends in the number of particles that adhere to each other and in the geometry of the molecule.
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Hypervalent iodine catalyzed generation of nitrile oxides from oximes and their cycloaddition with alkenes or alkynes.
Akira Yoshimura,Kyle R. Middleton,Anthony D. Todora,Brent J. Kastern,Steven R. Koski,Andrey V. Maskaev,Viktor V. Zhdankin +6 more
TL;DR: This reaction involves active hypervalent iodine species formed in situ from catalytic iodoarene and oxone in the presence of hexafluoroisopropanol in aqueous methanol solution.
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Iodine catalysis: A green alternative to transition metals in organic chemistry and technology
TL;DR: Iodine and compounds of iodine in higher oxidation states have emerged as versatile and environmentally benign reagents for organic chemistry as mentioned in this paper, leading to the formation of new C O, C N, and C C C bonds in organic compounds.
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Organocatalytic syntheses of benzoxazoles and benzothiazoles using aryl iodide and oxone via C-H functionalization and C-O/S bond formation.
TL;DR: An organocatalytic protocol for the syntheses of 2-substituted benzoxazoles and benzothiazoles using 1-iodo-4-nitrobenzene as catalyst and oxone as an inexpensive and environmentally safe terminal oxidant at room temperature in air via oxidative C-H functionalization and C-O/S bond formation is described.
References
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Hypervalent iodine reagents as a new entrance to organocatalysts
Toshifumi Dohi,Yasuyuki Kita +1 more
TL;DR: The historical background and the efforts made to realize the catalytic utilization of hypervalent iodine reagents are highlighted, especially with focus on iodine(iii).
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Hypervalent iodine-mediated oxidation of alcohols
Muhammet Uyanik,Kazuaki Ishihara +1 more
TL;DR: The design of hypervalent iodine catalysts is focused on and the discovery and development of the oxidation of alcohols with the stoichiometric or catalytic use of hyperValent iodine compounds is reviewed.