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Organic conducting polymers derived from substituted thiophenes as electrochromic material

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This article is published in Journal of Electroanalytical Chemistry.The article was published on 1983-06-24. It has received 290 citations till now. The article focuses on the topics: Electrochromism & Conductive polymer.

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First evidence of crystalline structure in conducting polythiophene

TL;DR: In this article, the effect of structure and dopant on organic conducting polymers was analyzed and a coil structure for this organic conducting polymer was proposed, where trifluoromethylsulphonate anion was the best fitting dopant.
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Electrochemically Induced Volume Changes in Poly(3,4-ethylenedioxythiophene)

TL;DR: In this paper, the bending beam method was used to detect volume changes during electrochemical transformations of poly(3,4-ethylenedioxythiophene) and found that the volume changes cannot be explained as a simple consequence of ion transport but must be due to the structural change of the polymer between different states.
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Redox Behavior and Electrochromic Properties of Polypyrrole Films in Aqueous Solutions

TL;DR: In this article, the change in film color which occurs in the redox reaction of the film was investigated in detail as a function of electrode potential and the charge consumed in the reaction.
References
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Journal ArticleDOI

The electrochromic properties of lutetium and other phthalocyanines

TL;DR: In this paper, the electrochemical properties of thin films of metal phthalocyanines on conducting substrates are investigated and a film electrode model is proposed based on an irreversible charge transfer step.
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Mechanism of electrochromism in WO3

TL;DR: In this article, it was shown that the positive ion remains fully ionized even in the presence of high densities of injected electrons in amorphous WO3 films and in tungsten bronzes.
Journal ArticleDOI

Electrochromism in Li x WO 3

TL;DR: In this article, the electrochromic behavior of symmetric and asymmetric cells has been studied by potentiostatic and galvanostatic measurements for both asymmetric and symmetric cells, and the kinetics of coloration and bleaching are ascribed to barrier-limited and space charge-limited current flow, respectively.
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