Journal ArticleDOI
Organometallic Electrochemistry: Origins, Development, and Future
TLDR
In this article, the evolution of organotransition metal electrochemistry from its origin with ferrocene to its promise in future applications is presented, where key findings on the relationships of electron transfer to molecular structures and to the reactions of OMT metal complexes are given.About:
This article is published in Organometallics.The article was published on 2007-10-25. It has received 205 citations till now.read more
Citations
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Journal ArticleDOI
Why is Ferrocene so Exceptional
TL;DR: Ferrocene's chemistry, properties, functions, and applications can be found in a literature survey by as discussed by the authors, with a focus on basic properties, including ligand-exchange reactions and the ferrocene/ferricinium redox couple.
Journal ArticleDOI
Recent Advances in C–H Functionalization Using Electrochemical Transition Metal Catalysis
Cong Ma,Ping Fang,Tian-Sheng Mei +2 more
TL;DR: In this paper, a review summarizes recent progress in merging electrochemistry with transition metal-catalyzed C-H functionalization, specifically C-C, C-X (halogen), C−O, C−P, and C−N bond formation.
Journal ArticleDOI
Spectroelectrochemistry: the best of two worlds
Wolfgang Kaim,Jan Fiedler +1 more
TL;DR: Practical considerations and guidelines are provided in this tutorial review, and selected examples involving UV-VIS-NIR and IR absorption spectroscopy as well as electron paramagnetic resonance (EPR) are presented to illustrate the potential and the applicability of this technique.
Journal ArticleDOI
Organometallic Electrochemistry Based on Electrolytes Containing Weakly-Coordinating Fluoroarylborate Anions
TL;DR: A series of studies on transition metal sandwich and half-sandwich compounds yielded an integrated model of how to use solvent-electrolyte combinations to manipulate the E, and gave the first definitive in situ characterization of their radical cations.
Journal ArticleDOI
Palladium-Catalyzed C(sp3)-H Oxygenation via Electrochemical Oxidation.
TL;DR: This work reports an electrochemical strategy that takes advantage of anodic oxidation of PdII to induce selective C-O reductive elimination with a variety of oxyanion coupling partners.
References
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Journal ArticleDOI
Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more
TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
Journal ArticleDOI
Chemical and Electrochemical Electron-Transfer Theory
TL;DR: In this article, a review of electron transfer reactions is presented, focusing on the absence of bond rupture in the reaction step, which is a unique feature of purely electron-transfer reactions.
Journal ArticleDOI
Chemical Redox Agents for Organometallic Chemistry
TL;DR: 1. Advantages and disadvantages of Chemical Redox Agents, 2. Reversible vs Irreversible ET Reagents, 3. Categorization of Reagent Strength.
Journal ArticleDOI
Equilibrium Acidities in Dimethyl Sulfoxide Solution
TL;DR: The first acidity scale to be established in a pure solvent other than water was the result of the pioneering work of Conant, Wheland, and McEwen in ether or ben~ene.
Journal ArticleDOI
Ferrocene-mediated enzyme electrode for amperometric determination of glucose.
Anthony E. G. Cass,Graham Davis,Francis Gd,Hugh Allen Oliver Hill,W.J. Aston,I.J. Higgins,E. V. Plotkin,Scott Ld,Anthony Turner +8 more
TL;DR: Type III adenosine deaminase would be the best choice for the construction of an immobilized enzyme electrode both from the point of view of apparent Km and Vmax values and from the less pronounced product inhibition effect on the type III enzyme compared to the Type V enzyme.