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PhI Catalyzed Acetoxyselenylation and Formyloxyselenylation of Alkenes

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This article is published in Helvetica Chimica Acta.The article was published on 2017-03-01. It has received 9 citations till now. The article focuses on the topics: Catalysis.

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Electrochemical Aminoselenation and Oxyselenation of Styrenes with Hydrogen Evolution

TL;DR: The electro-induced aminoselenation and oxyselenation of styrenes without any acids or oxidants as additives is reported and this transformation is compatible with various functional groups, which leads to vicinal difunctionalized organoselenium compounds.
Journal ArticleDOI

Alkene Difunctionalization Using Hypervalent Iodine Reagents: Progress and Developments in the Past Ten Years.

TL;DR: This review outlines the main advances in the past 10 years in regard to alkene heterofunctionalization chemistry using achiral and chiral hypervalent iodine reagents and catalysts.
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Visible light-promoted, iodine-catalyzed selenoalkoxylation of olefins with diselenides and alcohols in the presence of hydrogen peroxide/air oxidant: an efficient access to α -alkoxyl selenides

TL;DR: In this paper, a selenoalkoxylation of olefins with diselenides and alcohols can be efficiently achieved in the presence of only 0.5 equiv. of H2O2.
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Iodine-mediated acyloxyselenenylation of alkenes

TL;DR: This metal-free iodine-mediated acyloxyselenenylation proceeds efficiently under mild reaction conditions, affording a series of 2-acyloxy-1-selenides with high regioselectivity and in moderate to good yields.
References
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Journal ArticleDOI

Chemistry of Polyvalent Iodine

TL;DR: The present review summarizes the data that appeared in the literature following publication of previous reviews in 1996 and 2002 and is organized according to the classes of organic polyvalent iodine compounds with emphasis on their synthetic application.
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Advances in Synthetic Applications of Hypervalent Iodine Compounds

TL;DR: One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.
Journal ArticleDOI

Selenium in cancer prevention: a review of the evidence and mechanism of action

TL;DR: Current primary and secondary prevention trials of Se are underway in the USA, including the Selenium and Vitamin E Cancer Prevention Trial (SELECT) relating to prostate cancer, although a large European trial is still desirable given the likelihood of a stronger effect in populations of lower Se status.
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