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Phosphorus- and Sulfur-Containing High-Refractive-Index Polymers with High Tg and Transparency Derived from a Bio-Based Aldehyde
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In this article, two flexible and colorless polymers are synthesized based on a phosphorus-containing derivative of a bio-based aromatic aldehyde (4-hydroxybenzaldehyde) by a thiol-ene reaction.Abstract:
Two flexible and colorless polymers are synthesized based on a phosphorus-containing derivative of a bio-based aromatic aldehyde (4-hydroxybenzaldehyde) by a thiol-ene reaction. Thanks to the high ...read more
Citations
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Journal ArticleDOI
Photoclick Chemistry: A Bright Idea.
Benjamin D. Fairbanks,Laura J. Macdougall,Sudheendran Mavila,Jasmine Sinha,Bruce E. Kirkpatrick,Kristi S. Anseth,Christopher N. Bowman +6 more
TL;DR: The photoclick chemistry as discussed by the authors is a collection of click reactions that are performed via the application of light, and it has had diverse impact over a broad range of chemical and biological research due to the spatiotemporal control, high selectivity, and excellent product yields afforded by the combination of light and click chemistry.
Journal ArticleDOI
Synthesis, photoluminescence properties and sensing applications of luminescent sulfur nanodots
TL;DR: This review systematically introduces the synthesis methods, characterization, PL mechanisms and some typical applications of S-dots in chemical sensing, as the PL quantum yield (QY) is a key factor to evaluate the performance of luminescent materials.
Journal ArticleDOI
High Refractive Index Photopolymers by Thiol-Yne "Click" Polymerization.
Sudheendran Mavila,Jasmine Sinha,Yunfeng Hu,Maciej Podgórski,Maciej Podgórski,Parag K. Shah,Christopher N. Bowman +6 more
TL;DR: A scalable synthesis of high refractive index, optically transparent photopolymers from a family of low-viscosity multifunctional thiol and alkyne monomers via thiol-yne "click" is described in this article.
Journal ArticleDOI
Catalyst-Free Click Polymerization of Thiol and Activated Internal Alkynes: A Facile Strategy toward Functional Poly(β-thioacrylate)s
TL;DR: In this paper, the authors describe the use of thiol-yne click polymerization for the construction of linear and hyperbranched polysulfides with advanced functionalities.
Journal ArticleDOI
Algae-Inspired, Sulfur-Based Polymer with Infrared Transmission and Elastic Function
TL;DR: In this paper, an elastic material with an infrared (IR)-transmitting property based on the structural features of algae oils was presented, and the bulk copolymerization of elemental sulfur and unsaturated hyd...
References
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Journal ArticleDOI
High refractive index polymers: fundamental research and practical applications
Jingang Liu,Mitsuru Ueda +1 more
TL;DR: In this paper, a review of recent developments in optical high-refractive-index polymers and their typical applications in high-tech fields is presented, including the optical dispersion (Abbe number), birefringence and optical transparency.
Journal ArticleDOI
Recent Progress in High Refractive Index Polymers
TL;DR: High refractive index polymers have been widely developed in recent years for their potential applications in advanced optoelectronic fabrications, such as high performance components for advanced display devices, encapsulants for light-emitting diode devices, microlens components for complementary metal oxide semiconductor image sensors, plastic lenses for eyeglasses, and camera, pick-up, and projector lenses as mentioned in this paper.
Journal ArticleDOI
New Infrared Transmitting Material via Inverse Vulcanization of Elemental Sulfur to Prepare High Refractive Index Polymers
Jared J. Griebel,Soha Namnabat,Eui Tae Kim,Roland Himmelhuber,Dominic H. Moronta,Woo Jin Chung,Adam G. Simmonds,Kyung-Jo Kim,John D. van der Laan,Ngoc A. Nguyen,Eustace L. Dereniak,Michael E. Mackay,Kookheon Char,Richard S. Glass,Robert A. Norwood,Jeffrey Pyun +15 more
TL;DR: High quality imaging in the near (1.5 μm) and mid-IR regions using high refractive index polymeric lenses from these sulfur materials was demonstrated.
Journal ArticleDOI
Vanillin, a key-intermediate of biobased polymers
TL;DR: The use of vanillin for the preparation of renewable polymers is a burning issue that is actively investigated as mentioned in this paper, and vanillin is currently one of the only biobased and aromatic compounds that are industrially available.
Journal ArticleDOI
Anti-reflective optical coatings incorporating nanoparticles
TL;DR: Results demonstrate that it is possible to fabricate a polymeric thin film of continuously tunable refractive index over a wide range by loading the film with varying concentrations of metal oxide nanoparticles.
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High refractive index polymers: fundamental research and practical applications
Jingang Liu,Mitsuru Ueda +1 more