Journal ArticleDOI
Photochemical tuning of light emission in a conjugated polymer containing norbornadiene units in the main chain
Francesco Babudri,Gianmarco Bilancia,Antonio Cardone,Paolo Coppo,Luisa De Cola,Gianluca M. Farinola,Johannes W. Hofstraat,Francesco Naso +7 more
TLDR
A conjugated alternating copolymer containing norbornadiene and bis(ethynylene)phenylene units was prepared by the Cassar-Heck-Sonogashira cross-coupling reaction and its electroluminescence was tested in a device, and its fluorescence colour could be tuned by light-induced nor bornadiene-quadricyclane isomerization.Abstract:
A conjugated alternating copolymer containing norbornadiene and bis(ethynylene)phenylene units was prepared by the Cassar-Heck-Sonogashira cross-coupling reaction. Its electroluminescence was tested in a device, and its fluorescence colour could be tuned by light-induced norbornadiene-quadricyclane isomerization.read more
Citations
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Journal ArticleDOI
Low Molecular Weight Norbornadiene Derivatives for Molecular Solar-Thermal Energy Storage.
Maria Quant,Anders Lennartson,Ambra Dreos,Mikael Kuisma,Paul Erhart,Karl Börjesson,Karl Börjesson,Kasper Moth-Poulsen +7 more
TL;DR: The synthesis, characterization, and computational evaluation of a series of low molecular weight norbornadiene–quadricyclane systems indicate that the ethynyl moiety plays a critical role in obtaining the high oscillator strengths seen for these molecules.
Journal ArticleDOI
Unraveling factors leading to efficient norbornadiene–quadricyclane molecular solar-thermal energy storage systems
Kjell Jorner,Ambra Dreos,Rikard Emanuelsson,Ouissam El Bakouri,Ignacio Fernández Galván,Karl Börjesson,Karl Börjesson,Ferran Feixas,Roland Lindh,Burkhard Zietz,Kasper Moth-Poulsen,Henrik Ottosson +11 more
TL;DR: In this article, a series of norbornadiene-quadricyclane (NBD-R2) doubly substituted at the C7-position with R = H, Me, and iPr was studied.
Journal ArticleDOI
Synthesis of Functionalized Aryleneethynylene Oligomers and Polymers for Organic Electronics by Pd-Catalyzed Coupling Reactions
Alessandra Operamolla,Roberta Ragni,Omar Hassan Omar,Giuliano Iacobellis,Antonio Cardone,Francesco Babudri,Gianluca M. Farinola +6 more
TL;DR: In this paper, the authors discuss synthetic routes to organic conjugated oligomers and polymers bearing triple C-C bonds that have been recently developed in our laboratories, based on Pd-catalyzed Csp-Csp 2 coupling reactions.
Journal ArticleDOI
Turn-off mode fluorescent norbornadiene-based photoswitches
TL;DR: To explore the potential of negative photochromic molecules for possible optical memory storage applications, a series of four norbornadiene–quadricyclane (NBD–QC) photoswitching molecules are synthesized and studied.
OtherDOI
Norbornadiene/Quadricyclane ( <scp>NBD</scp> / <scp>QC</scp> ) and Conversion of Solar Energy
TL;DR: In this paper , the norbornadiene (NBD) molecule was used as a photoswitch to obtain a high-energy metastable isomer quadricyclane (QC) via light-induced cycloaddition reaction.
References
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