Journal ArticleDOI
Photoinduced Electron Transfer in Solution: Exciplex and Radical Ion Pair Formation Free Enthalpies and their Solvent Dependence
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This article is published in Zeitschrift für Physikalische Chemie.The article was published on 1982-01-01. It has received 940 citations till now. The article focuses on the topics: Photoinduced electron transfer & Radical ion.read more
Citations
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Study on emission quenching by 2,2,6,6-tetramethyl-1-piperidinyloxy free radical
TL;DR: In this article, the emission quenching mechanism of four emissive compounds by 2,2,6,6-tetramethyl-1-piperidinyloxy free radical (TEMPO) was investigated using steady state and transient state spectroscopy.
Journal ArticleDOI
Primary processes in the thiacyanine dimer-photosensitized reduction of p-nitroacetophenone in water by
TL;DR: In this paper, the reduction of p-nitroacetophenone (p-NAP) by ascorbic acid (AA) in water photosensitized by thiacyanine dimers M22− have been considered.
Book ChapterDOI
The Cyclization of Polymer Chains in Solution
TL;DR: This chapter provides a review of pertinent theoretical concepts and a description of experiments, based upon luminescence spectroscopy, which allow one to examine the predictions of the theory.
Journal ArticleDOI
A study on photo-induced intramolecular electron-transfer in fullerene-benzothiadiazole-triphenylamine using time-dependent density functional theory
TL;DR: In this article, the photo-induced charge separation (kCS) and charge recombination rate constants (kCR) were calculated using Marcus theory, and the results showed the calculated kCS and observed kCS of C60-PBTD-TPA correspond to each other, however, the both of TPA differ by two orders of magnitude.
Journal ArticleDOI
Photochemical transformations. 49. Solvent effects on singlet ionic and triplet photoreactions of some bridged polycyclic chlorides: Comparison with ground-state reactions†‡
TL;DR: In this paper, direct irradiations of 2-chloro-6,7 : 8,9-dibenzotricyclo [3.2.2] nona-6-8-diene (5-Cl) were conducted in cyclohexane, acetic acid and wet acetonitrile.
References
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Journal ArticleDOI
Dipolar Nature of Molecular Complexes Formed in the Excited State
Journal ArticleDOI
Solvent, isotope, and magnetic field effects in the geminate recombination of radical ion pairs
TL;DR: In this article, the magnetic field dependence of the geminate recombination triplet yield of radical ion pairs generated via photoinduced electron transfer in polar solvents is investigated for the systems pyrene/N, Ndimethylaniline (Py/DMA), pyrene 3,5,dimethoxy•N,Ndimethynylinox•N and pyrene DMDMA, and the perdeuterated system Py•d10/dMA•d11.
Journal ArticleDOI
Bindungszustand und Fluoreszenzspektren von Hetero-Excimeren
Dieter Rehm,Albert Weller +1 more
TL;DR: The structureless fluorescence spectra of more than one hundred heteroexcimers (unsymmetrical molecular complexes which are stable in the excited state) were measured in hexane or other inert solvents.