Journal ArticleDOI
Photoinduced Electron Transfer in Solution: Exciplex and Radical Ion Pair Formation Free Enthalpies and their Solvent Dependence
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This article is published in Zeitschrift für Physikalische Chemie.The article was published on 1982-01-01. It has received 940 citations till now. The article focuses on the topics: Photoinduced electron transfer & Radical ion.read more
Citations
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Electrogenerated chemiluminescence from derivatives of aluminum quinolate and quinacridones: Cross-reactions with triarylamines lead to singlet emission through triplet-triplet annihilation pathways
Erin M. Gross,Jeffrey D. Anderson,A. F. Slaterbeck,Sankaran Thayumanavan,Stephen Barlow,Yueteng Zhang,Seth R. Marder,H. K. Hall,M. Flore Nabor,J. F. Wang,Eugene A. Mash,Neal R. Armstrong,R. M. Wightman +12 more
TL;DR: In this paper, a solution electrogenerated chemiluminescence (ECL) was evaluated for molecules of interest for organic light-emitting diodes (OLEDs), using high-frequency voltage pulses at a microelectrode.
Journal ArticleDOI
Optimized Electron Transfer in Charge-Transfer Ion Pairs. Pronounced Inner-Sphere Behavior of Olefin Donors
TL;DR: In this article, a tunable, high-power pump-probe spectrometer based on a Ti:sapphire laser with 250-fs resolution was proposed for time-resolved (fs) spectroscopy.
Journal ArticleDOI
Photoinduced Electron Transfer on the Surfaces of Micelles
TL;DR: In this article, photoinduced electron transfer between N,N-dimethylaniline (DMA) and octadecylrhodamine B (ODRB) was studied on the surfaces of three alkyltrimethylammonium bromide micelles.
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Ion Pairing and Electron Transfer
TL;DR: In this paper, the effect of electrolytes on the rates of electron transfer reactions is discussed. But the authors make a distinction between ion reorganization (case (iii)) and the formation of real chemical intermediates.
Journal ArticleDOI
Application of Visible-to-UV Photon Upconversion to Photoredox Catalysis: The Activation of Aryl Bromides
TL;DR: The activation of aryl-Br bonds was achieved by sequential combination of a triplet-triplet annihilation process of the organic dyes, butane-2,3-dione and 2,5-diphenyloxazole, with a single-electron-transfer activation ofAryl bromides.
References
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Journal ArticleDOI
Dipolar Nature of Molecular Complexes Formed in the Excited State
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Solvent, isotope, and magnetic field effects in the geminate recombination of radical ion pairs
TL;DR: In this article, the magnetic field dependence of the geminate recombination triplet yield of radical ion pairs generated via photoinduced electron transfer in polar solvents is investigated for the systems pyrene/N, Ndimethylaniline (Py/DMA), pyrene 3,5,dimethoxy•N,Ndimethynylinox•N and pyrene DMDMA, and the perdeuterated system Py•d10/dMA•d11.
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Bindungszustand und Fluoreszenzspektren von Hetero-Excimeren
Dieter Rehm,Albert Weller +1 more
TL;DR: The structureless fluorescence spectra of more than one hundred heteroexcimers (unsymmetrical molecular complexes which are stable in the excited state) were measured in hexane or other inert solvents.