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Photoinitiators and photoinitiation, 7. The photo‐induced α‐cleavage of acylphosphine oxides. Trapping of primary radicals by a stable nitroxyl

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This article is published in Die Makromolekulare Chemie, Rapid Communications.The article was published on 1987-06-01. It has received 31 citations till now. The article focuses on the topics: Nitroxyl.

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Direct annulations toward phosphorylated oxindoles: silver-catalyzed carbon-phosphorus functionalization of alkenes.

TL;DR: This paper aims to demonstrate the efforts towards in-situ applicability of EMMARM, as to provide real-time information about concrete mechanical properties such as E-modulus and compressive strength in the response of the immune system to EMTs.
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Reaction Mechanism of Monoacyl- and Bisacylphosphine Oxide Photoinitiators Studied by 31P-, 13C-, and 1H-CIDNP and ESR

TL;DR: In this paper, a modification of Kaptein's rules for the 13C-NMR-CIDNP spectra was used to investigate the formation and reaction of phosphorus-centered radicals obtained from phosphorus-containing photoinitiators.
Journal ArticleDOI

Recent developments in photoinitiators

TL;DR: In this paper, a photoinitiator, bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide (1), has been developed for industrial applications.
Journal ArticleDOI

A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

TL;DR: The first Cu(i)-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles is reported, producing hydrogen ( H2) as the only byproduct.
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