Journal ArticleDOI
Physical properties of polypyrrole films containing sulfonated metallophthalocyanine anions
TLDR
In this paper, thin films of polypyrrole (PPy) containing tetrasulfonated metallophthalocyanine anions (MTsPc 4−, MCu, Ni and Co) were prepared electrochemically from aqueous solution in a single-compartment cell.About:
This article is published in Synthetic Metals.The article was published on 1992-05-01. It has received 43 citations till now. The article focuses on the topics: Polypyrrole.read more
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Journal ArticleDOI
Metallophthalocyanine-based molecular materials as catalysts for electrochemical reactions
TL;DR: In this article, the authors show that the formal potential of a metallophthalocyanine complex needs to be in a rather narrow potential window for achieving maximum activity, probably corresponding to surface coverages of an M-molecule adduct equal to 0.5.
Journal ArticleDOI
Polypyrrole films containing metal complexes : syntheses and applications
TL;DR: In this article, a method to prepare polymer coatings on a carrier electrode based on electropolymerization of pyrrole and substituted pyrroles is described, and an overview of prospective applications is given.
Journal ArticleDOI
Immobilization of metalloporphyrins in electropolymerized films: design and applications
Journal ArticleDOI
Tuning the redox properties of metalloporphyrin- and metallophthalocyanine-based molecular electrodes for the highest electrocatalytic activity in the oxidation of thiols
Fethi Bedioui,Sophie Griveau,Tebello Nyokong,A. John Appleby,Claudia A. Caro,Miguel Gulppi,Gonzalo Ochoa,José H. Zagal +7 more
TL;DR: For a great variety complexes bearing the same metal center (Co), correlations between log i and E(o') of the Co(II)/Co(I) couple have the shape of an unsymmetric volcano, indicating that the potential of the co-operation couple can be tuned using the appropriate ligand to achieve maximum catalytic activity.
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Modified Polypyrrole with Tetrasulfonated Nickel Phthalocyanine as a Fiber for Solid-Phase Microextraction. Application to the Extraction of BTEX Compounds from Water Samples
TL;DR: In this article, gold wire was coated with polypyrrole (PPY) by electropolymerization and used as a solid phase microextraction (SPME) fiber.
References
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Electronic processes in non-crystalline materials
TL;DR: The Fermi Glass and the Anderson Transition as discussed by the authorsermi glass and Anderson transition have been studied in the context of non-crystalline Semiconductors, such as tetrahedrally-bonded semiconductors.
Journal ArticleDOI
Electrochemical polymerization of pyrrole
TL;DR: The electrochemical polymerization of pyrrole on platinum produces a strongly adhered, durable film with enhanced conductivity and good electrode properties as mentioned in this paper, which can be used to construct a durable film.
Journal ArticleDOI
Complexes Derived from Strong Field Ligands. XIX. Magnetic Properties of Transition Metal Derivatives of 4,4',4",4'''-Tetrasulfophthalocyanine
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The determination of structural properties of dimeric transition metal ion complexes from epr spectra
Thomas D. Smith,John R. Pilbrow +1 more
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Electron-spin-resonance studies of pyrrole polymers: Evidence for bipolarons
TL;DR: In this paper, it was deduced that the ESR signal seen in the as-prepared material does not arise from the current-carrying species, but rather from accidental neutral ''ensuremath{\pi}$-radical defects''.