Journal ArticleDOI
Pickering emulsion polymerized poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polystyrene composite particles and their electric stimuli-response
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TLDR
In this paper, a facile synthesis of Pickering emulsion polymerized poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polystyrene (PEDOT:PSS/PS) composite particles and their electro-responsive electrorheological (ER) characteristics when dispersed in silicone oil was reported.Abstract:
We report a facile synthesis of Pickering emulsion polymerized poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polystyrene (PEDOT:PSS/PS) composite particles and their electro-responsive electrorheological (ER) characteristics when dispersed in silicone oil. The PEDOT:PSS particles act both as a solid surfactant for the Pickering emulsion polymerization and as an electro-responsive activator for PEDOT:PSS/PS composite particles. The morphology, chemical structure, and thermal properties of the synthesized PEDOT:PSS/PS composite particles were determined by scanning electron microscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis, respectively. Moreover, the formation of chain structures by the dispersed particles was confirmed directly by optical microscopy. The rheological response of PEDOT:PSS/PS-based ER fluid in the presence of an electric field, examined using a rotational rheometer, represented ER effects with typical Bingham fluid behavior.read more
Citations
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TL;DR: In this paper, a seeded swelling polymerization process was used to synthesize polystyrene/polyaniline (PS/PANI) particles, in which an aniline monomer was initially absorbed into the PS particles due to ππ* stacking interactions and an initiation step of the polymerization of ferric ions added.
References
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Journal ArticleDOI
Poly(3,4‐ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future
TL;DR: An overview of 3,4-ethylenedioxythiophene (PEDT) and its derivatives can be found in this article, along with a description of the broad array of properties accessible and a set of the more prominent applications in which they can be utilized.
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Functional polymer microspheres
TL;DR: In this paper, examples of the above-mentioned functional particles are reviewed and discussed, including absorbents, latex diagnostics, affinity bioseparators and drug and enzyme carriers.
Journal ArticleDOI
Microencapsulation of octadecane as a phase-change material by interfacial polymerization in an emulsion system
TL;DR: In this paper, micro-capsules of about 1 μm in diameter were prepared using an interfacial polycondensation method with toluene-2,4-diisocyanate (TDI) and diethylenetriamine (DETA) as monomers in an emulsion system.
Journal ArticleDOI
In situ stabilized carbon nanofiber (CNF) reinforced epoxy nanocomposites
TL;DR: In this article, a functional amine terminated groups via silanization is introduced to improve the dispersion of carbon nanofibers and improve the interfacial interaction between CNFs and monomers.