Journal ArticleDOI
Progress in the synthesis and transformations of alkylidenecyclopropanes and alkylidenecyclobutanes.
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This article is published in Chemical Reviews.The article was published on 2014-06-13. It has received 208 citations till now.read more
Citations
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Recent Methodologies That Exploit C-C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes
TL;DR: The focus is on transition-metal-catalyzed processes that are triggered by C-C bond activation and β-carbon elimination, with the review concentrating on developments from mid-2009 to mid-2016.
Book
Comprehensive heterocyclic chemistry on CD-ROM
TL;DR: The comprehensive Heterocyclic Chemistry was published in 1984 and is now available on CD-ROM as discussed by the authors. But it is not available on the Internet yet, as it was not available before 1984.
Journal ArticleDOI
"Cut and Sew" Transformations via Transition-Metal-Catalyzed Carbon-Carbon Bond Activation.
TL;DR: The transition metal-catalyzed "cut and sew" transformation has recently emerged as a useful strategy for preparing complex molecular structures.
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Catalytic Enantioselective Ring-Opening Reactions of Cyclopropanes.
TL;DR: The development of enantioselective methods for the ring opening of cyclopropanes has grown from a proof of concept stage to a broad range of methods for accessing enantioenriched building blocks, and further extensive developments can be expected in the future.
Journal ArticleDOI
Gold-Catalyzed Synthesis of Small Rings.
TL;DR: This review aims to provide a comprehensive summary of all the major advances and discoveries made in the gold-catalyzed synthesis ofcyclopropanes, cyclopropenes, cyclobutanes, Cyclobutenes, and their corresponding heterocyclic or heterosubstituted analogs.
References
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Journal ArticleDOI
Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.
TL;DR: A number of improvements have developed the former process into an industrially very useful and attractive method for the construction of aryl -aryl bonds, but the need still exists for more efficient routes whereby the same outcome is accomplished, but with reduced waste and in fewer steps.
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Transition Metal-Mediated Cycloaddition Reactions
TL;DR: The phytochemical remains of the seven-membered ring formation are still under investigation, but it is clear that the polymethine content of the ring is lower than previously thought, suggesting that it is more likely to be a mixture of 22π and 32σ.
Journal ArticleDOI
Helical polymers: synthesis, structures, and functions
TL;DR: The chiral stationary phase for high-performance liquid chromatography showed good chiral recognition ability towards various racemates, including polyene and polymethine, which is useful for selective separation of chiral components from polyene-like molecules.
Journal ArticleDOI
Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins
Shinji Murai,Fumitoshi Kakiuchi,S. Sekine,Yasuo Tanaka,Asayuki Kamatani,Motohiro Sonoda,Naoto Chatani +6 more
TL;DR: The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds.
Journal ArticleDOI
Catalytic C−H/Olefin Coupling
Fumitoshi Kakiuchi,Shinji Murai +1 more
TL;DR: In this paper, the cleavage and addition of ortho C−H bonds in various aromatic compounds such as ketones, esters, imines, imidates, nitrile, and aldehydes to olefins and acetlylenes can be achieved with the aid of ruthenium catalysts.