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Journal ArticleDOI

Recent advances on polyoxometalate-based molecular and composite materials

TLDR
This critical review summarizes recent progress on POM-based molecular and composite materials, and particularly highlights the emerging areas that are closely related to surface, electronic, energy, environment, life science, etc.
Abstract
Polyoxometalates (POMs) are a subset of metal oxides with unique physical and chemical properties, which can be reliably modified through various techniques and methods to develop sophisticated materials and devices. In parallel with the large number of new crystal structures reported in the literature, the application of these POMs towards multifunctional materials has attracted considerable attention. This critical review summarizes recent progress on POM-based molecular and composite materials, and particularly highlights the emerging areas that are closely related to surface, electronic, energy, environment, life science, etc. (171 references).

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Catalytic applications of layered double hydroxides: recent advances and perspectives

TL;DR: This Review article is mainly focused on the most recent developments in smart design strategies for LDH materials and the potential catalytic applications of the resulting materials.
Journal ArticleDOI

Photochromism into nanosystems: towards lighting up the future nanoworld.

TL;DR: This Review provides an account of the recent advancements in reversible photocontrol of the structures and functions of photochromic nanosystems and their applications and outlines the challenges that need to be addressed and the opportunities that can be tapped into.
Journal ArticleDOI

Polyoxometalate-functionalized nanocarbon materials for energy conversion, energy storage and sensor systems

TL;DR: In this article, the authors summarize the latest progress in polyoxometalates (POMs) and carbon nanotubes (CNTs) nanocomposites with a focus on energy materials for water splitting and fuel cells, composite electrode materials for batteries and supercapacitors as well as composites for environmental pollutant sensing.
References
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Journal ArticleDOI

Transformation of carbon dioxide.

TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.
Journal ArticleDOI

Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

TL;DR: Inorganic metal-oxygen cluster anions form a class of compounds that is unique in its topological and electronic versatility and is important in several disciplines, such as analytical and clinical chemistry, catalysis (including photocatalysis), biochemistry, and medicine (antitumoral, antiviral, and even anti-HIV activity) as mentioned in this paper.
Journal ArticleDOI

Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices

TL;DR: In this critical review the synthetic and design approaches to the many polyoxometalate cluster types are presented encompassing all the sub-types of polyxometalates including, isopolyoxometAlates, heteropolyoxometricalates, and reduced molybdenum blue systems.
Journal ArticleDOI

Polyoxometalates: Building Blocks for Functional Nanoscale Systems

TL;DR: The possibilities of creating highly sophisticated functional hierarchical systems with multiple, interdependent, functionalities along with a critical analysis that allows the non-specialist to learn the salient features of POMs are discussed.
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