Journal ArticleDOI
Transformation of carbon dioxide.
TLDR
Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.Abstract:
4.3. Reaction Mechanism 2373 4.4. Asymmetric Synthesis 2374 4.5. Outlook 2374 5. Alternating Polymerization of Oxiranes and CO2 2374 5.1. Reaction Outlines 2374 5.2. Catalyst 2376 5.3. Asymmetric Polymerization 2377 5.4. Immobilized Catalysts 2377 6. Synthesis of Urea and Urethane Derivatives 2378 7. Synthesis of Carboxylic Acid 2379 8. Synthesis of Esters and Lactones 2380 9. Synthesis of Isocyanates 2382 10. Hydrogenation and Hydroformylation, and Alcohol Homologation 2382read more
Citations
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Journal ArticleDOI
Recent advances in catalytic hydrogenation of carbon dioxide
TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
Journal ArticleDOI
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
TL;DR: The challenges in achieving highly active and stable CO2 reduction electrocatalysts are analyzed, and several research directions for practical applications are proposed, with the aim of mitigating performance degradation, overcoming additional challenges, and facilitating research and development in this area.
Journal ArticleDOI
The teraton challenge. A review of fixation and transformation of carbon dioxide
TL;DR: In this paper, the authors present a review of CO2, its synthetic reactions and their possible role in future CO2 mitigation schemes that have to match the scale of man-made CO2 in the atmosphere, which rapidly approaches 1 teraton.
Journal ArticleDOI
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation
Aaron M. Appel,John E. Bercaw,Andrew Bruce Bocarsly,Holger Dobbek,Daniel L. DuBois,Michel Dupuis,James G. Ferry,Etsuko Fujita,Russ Hille,Paul J. A. Kenis,Cheryl A. Kerfeld,Cheryl A. Kerfeld,Robert H. Morris,Charles H. F. Peden,Archie R. Portis,Stephen W. Ragsdale,Thomas B. Rauchfuss,Joost N. H. Reek,Lance C. Seefeldt,Rudolf K. Thauer,Grover L. Waldrop +20 more
TL;DR: Providing a future energy supply that is secure and CO_2-neutral will require switching to nonfossil energy sources such as wind, solar, nuclear, and geothermal energy and developing methods for transforming the energy produced by these new sources into forms that can be stored, transported, and used upon demand.
Journal ArticleDOI
Frustrated Lewis pairs: metal-free hydrogen activation and more.
Douglas W. Stephan,Gerhard Erker +1 more
TL;DR: Sterically encumbered Lewis acid and Lewis base combinations do not undergo the ubiquitous neutralization reaction to form "classical" Lewis acid/Lewis base adducts, but both the unquenched Lewis acidity and basicity of such sterically "frustrated Lewis pairs (FLPs)" is available to carry out unusual reactions.
References
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Journal ArticleDOI
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
Hironori Arakawa,Michele Aresta,John Nelson Armor,Mark A. Barteau,Eric J. Beckman,Alexis T. Bell,John E. Bercaw,Carol Creutz,Eckhard Dinjus,David A. Dixon,Kazunari Domen,Daniel L. DuBois,Juergen Eckert,Etsuko Fujita,Dorothy H. Gibson,William A. Goddard,D. Wayne Goodman,Jay O. Keller,Gregory J. Kubas,Harold H. Kung,James E. Lyons,Leo Ernest Manzer,Tobin J. Marks,Keiji Morokuma,Kenneth M. Nicholas,Roy A. Periana,Lawrence Que,Jens Rostrup-Nielson,Wolfgang M.H. Sachtler,Lanny D. Schmidt,Ayusman Sen,Gabor A. Somorjai,Peter C. Stair,B. Ray Stults,William Tumas +34 more
TL;DR: The goal of the "Opportunities for Catalysis Research in Carbon Management" workshop was to review within the context of greenhouse gas/carbon issues the current state of knowledge, barriers to further scientific and technological progress, and basic scientific research needs in the areas of H2 generation and utilization.
Journal ArticleDOI
Catalytic functionalization of arenes and alkanes via C-H bond activation.
TL;DR: Several novel synthetic reactions of arenes and alkanes discovered and investigated in the laboratory are summarized here.
Journal ArticleDOI
Discrete Metal-Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism
TL;DR: Well-defined catalysts for epoxide-CO(2) copolymerization and related reactions are reviewed here.
Journal ArticleDOI
The chemistry of dimethyl carbonate.
Pietro Tundo,Maurizio Selva +1 more
TL;DR: DMC possesses properties of nontoxicity and biodegradability which makes it a true green reagent to use in syntheses that prevent pollution at the source and avoiding the formation of undesirable inorganic salts as byproducts.
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