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Relating Catalysis between Fuel Cell and Metal-Air Batteries

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TLDR
In this article, the authors bridge some of the ideas from fuel cell to metal-air batteries with the aim of inspiring new ideas and directions for future research, which can potentially utilize the electrical grid network for charging, bypassing the need for establishing a hydrogen infrastructure.
Abstract
Summary With the ever-increasing demand for higher-performing energy-storage systems, electrocatalysis has become a major topic of interest in an attempt to enhance the electrochemical performance of many electrochemical technologies. Discoveries pertaining to the oxygen reduction reaction catalyst helped enable the commercialization of fuel-cell-based electric vehicles. However, a closely related technology, the metal-air battery, has yet to find commercial application. Much like the Li-ion battery, metal-air batteries can potentially utilize the electrical grid network for charging, bypassing the need for establishing a hydrogen infrastructure. Among the metal-air batteries, Li-air and Zn-air batteries have drawn much interest in the past decade. Unfortunately, state-of-the art metal-air batteries still produce performances that are well below practical levels. In this brief perspective, we hope to bridge some of the ideas from fuel cell to that of metal-air batteries with the aim of inspiring new ideas and directions for future research.

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Citations
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Journal ArticleDOI

Recent advances of noble-metal-free bifunctional oxygen reduction and evolution electrocatalysts

TL;DR: In this article, the design principles to obtain high-performance noble-metal-free bifunctional oxygen electrocatalysts by emphasizing strategies of both intrinsic activity regulation and active site integration are systematically addressed.
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Oxygen Reduction Electrocatalysts toward Practical Fuel Cells: Progress and Perspectives

TL;DR: In this paper, the authors focus on the recent progress of ORR electrocatalysts in fuel cells and highlight the fundamental problems associated with insufficient activity translation from rotating disk electrode to membrane electrode assembly in the fuel cells.
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High‐Entropy Metal Sulfide Nanoparticles Promise High‐Performance Oxygen Evolution Reaction

TL;DR: In this article, the synthesis of high-entropy metal sulfide (HEMS) solid solution nanoparticles is reported, which exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity.
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Dynamic Behavior of Single-Atom Catalysts in Electrocatalysis: Identification of Cu-N3 as an Active Site for the Oxygen Reduction Reaction.

TL;DR: In this article, a two-step approach was developed to fabricate single-atom catalysts with a uniform and well-defined Cu2+-N4 structure that exhibits comparable activity and superior durability in comparison to Pt/C.
References
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Journal ArticleDOI

A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles.

TL;DR: The high activity of BSCF was predicted from a design principle established by systematic examination of more than 10 transition metal oxides, which showed that the intrinsic OER activity exhibits a volcano-shaped dependence on the occupancy of the 3d electron with an eg symmetry of surface transition metal cations in an oxide.
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Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability

TL;DR: It is demonstrated that the Pt3Ni( 111) surface is 10-fold more active for the ORR than the corresponding Pt(111) surface and 90-foldMore active than the current state-of-the-art Pt/C catalysts for PEMFC.
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Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces

TL;DR: A highly active and durable class of electrocatalysts is synthesized by exploiting the structural evolution of platinum-nickel (Pt-Ni) bimetallic nanocrystals by exploitingThe starting material, crystalline PtNi3 polyhedra, transforms in solution by interior erosion into Pt3Ni nanoframes with surfaces that offer three-dimensional molecular accessibility.
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Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries

TL;DR: These findings reflect the critical influences of the σ orbital and metal-oxygen covalency on the competition between O(2)(2-)/OH(-) displacement and OH(-) regeneration on surface transition-metal ions as the rate-limiting steps of the ORR, and highlight the importance of electronic structure in controlling oxide catalytic activity.
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Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts

TL;DR: The battery electrochemistry and catalytic mechanism of oxygen reduction reactions are discussed on the basis of aqueous and organic electrolytes, and the design and optimization of air-electrode structure are outlined.
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