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Removal of U(VI) from aqueous solutions by using MWCNTs and chitosan modified MWCNTs.

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TLDR
In this paper, the multwalled carbon nanotubes (MWCNTs) were modified with chitosan (CS) by using low temperature plasma grafting technique (denoted as MWCNT-CS).
Abstract
In this paper, the multiwalled carbon nanotubes (MWCNTs) were modified with chitosan (CS) by using low temperature plasma grafting technique (denoted as MWCNT-CS). The prepared MWCNTs and MWCNT-CS were characterized by SEM, TEM, FTIR and Raman spectroscopy in detail and the results suggested that CS molecules were successfully grafted on the surfaces of MWCNTs. The materials were applied as adsorbents in the removal of U(VI) ions from large volumes of aqueous solutions as a function of environmental conditions. The removal of U(VI) from aqueous solution to MWCNTs and MWCNT-CS increased with increasing pH values at pH   7. The sorption of U(VI) on MWCNTs and MWCNT-CS was strongly dependent on pH and independent of ionic strength. The sorption of U(VI) on MWCNTs and MWCNT-CS was dominated by inner-sphere surface complexation rather than by ion exchange or outer-sphere surface complexation. The surface grafted chitosan molecules can enhances U(VI) sorption on MWCNTs obviously, which was also evidenced from the XPS spectroscopy analysis. The results of high sorption capacity of U(VI) on MWCNT-CS suggest that the MWCNT-CS nanomaterial is a suitable candidate in the preconcentration of U(VI) ions from large volumes of aqueous solutions.

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Recent Modifications of Chitosan for Adsorption Applications: A Critical and Systematic Review

TL;DR: This work summarizes the published works of the last three years regarding the modification reactions of chitosans (grafting, cross-linking, etc.) and their application to adsorption of different environmental pollutants (in liquid-phase).
Journal ArticleDOI

Emerging natural and tailored materials for uranium-contaminated water treatment and environmental remediation

TL;DR: In this article, the authors provide a systematic and comprehensive overview of the researches conducted from 2005 to 2018 for removing uranium from aqueous solution by these emerging materials, including inorganic materials (e.g., clay minerals, metal oxides, mesoporous silica), organic polymers, carbon family materials, and porous framework materials.
Posted Content

Sorption of Eu(III) on Attapulgite Studied by Batch, XPS and EXAFS Techniques

TL;DR: In this paper, the effects of pH, ionic strength and temperature on the sorption of Eu(III) on attapulgite were investigated in the presence and absence of fulvic acid (FA) and humic acid (HA).
Journal ArticleDOI

Amidoxime-grafted multiwalled carbon nanotubes by plasma techniques for efficient removal of uranium(VI)

TL;DR: In this article, a solid phase extractant, amidoxime-grafted multiwalled carbon nanotubes (AO-g-MWCNTs), has been synthesized using plasma techniques to selectively separate uranium from nuclear industrial effluents.
Journal ArticleDOI

Facile synthesis of alumina-decorated multi-walled carbon nanotubes for simultaneous adsorption of cadmium ion and trichloroethylene

TL;DR: An adsorbent was prepared by decorating alumina onto the surface of multi-wall carbon nanotubes (MWCNTs) for simultaneous removal of cadmium ion (Cd(II) ion) and trichloroethylene (TCE) from groundwater as discussed by the authors.
References
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Journal ArticleDOI

Helical microtubules of graphitic carbon

Sumio Iijima
- 01 Nov 1991 - 
TL;DR: Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.
Journal ArticleDOI

Water conduction through the hydrophobic channel of a carbon nanotube

TL;DR: Observations suggest that carbon nanotubes, with their rigid nonpolar structures, might be exploited as unique molecular channels for water and protons, with the channel occupancy and conductivity tunable by changes in the local channel polarity and solvent conditions.
Journal ArticleDOI

Few-Layered Graphene Oxide Nanosheets As Superior Sorbents for Heavy Metal Ion Pollution Management

TL;DR: The graphene oxide nanosheets may be suitable materials in heavy metal ion pollution cleanup if they are synthesized in large scale and at low price in near future.
Journal ArticleDOI

Carbon nanotubes as adsorbents in environmental pollution management: A review

TL;DR: Carbon nanotubes (CNTs) have aroused widespread attention as a new type of adsorbents due to their outstanding ability for the removal of various inorganic and organic pollutants, and radionuclides from large volumes of wastewater as discussed by the authors.
Journal ArticleDOI

Sulfonated Graphene for Persistent Aromatic Pollutant Management

TL;DR: A kind of sulfonated graphene (around 3 nm thick) with high dispersion properties in aqueous solution capable of absorbing naphthalene and 1-naphthol aromatic pollutants from aqueously solutions is introduced.
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