Journal ArticleDOI
Role of the ceramic fillers in enhancing the transport properties of composite polymer electrolytes
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TLDR
In this article, a model to account for the role of the ceramic fillers in enhancing the transport properties of PEO-based composite polymer electrolytes is proposed, supported by a series of specifically addressed electrochemical tests which included the determination of the conductivity and of the lithium transference number of various composite electrolyte samples differing from the type of the surface states of a ceramic filler.About:
This article is published in Electrochimica Acta.The article was published on 2001-05-01. It has received 630 citations till now. The article focuses on the topics: Ceramic & Nanocomposite.read more
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Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
Zhigang Xue,Dan He,Xiaolin Xie +2 more
TL;DR: In this article, a review of the recent developments and issues concerning polyethylene oxide (PEO) based electrolytes for lithium-ion batteries is presented, including blending, modifying and making PEO derivatives.
Journal ArticleDOI
Recent advances in all-solid-state rechargeable lithium batteries
TL;DR: In this article, the authors reviewed the current state of all solid-state lithium batteries with major focus on the material aspects, including inorganic ceramic and organic solid polymer electrolyte materials, and emphasized the importance of the electrolytes and their associated interfaces with electrodes as well as their effects on the battery performance.
Journal ArticleDOI
Polymer electrolytes for lithium polymer batteries
TL;DR: In this article, state-of-the-art polymer electrolytes are discussed with respect to their electrochemical and physical properties for their application in lithium polymer batteries, and the incorporation of inorganic fillers into GPEs to improve their mechanical strength as well as their transport properties and electrochemical properties is discussed.
Journal ArticleDOI
PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic”
TL;DR: In this article, composites consisting of polyethylene-oxide/garnet electrolytes were fabricated for a safe solid-state Li-metal rechargeable battery, which achieved high discharge capacity (139.1% after 100 cycles) and high capacity retention (103.6% with coulombic efficiency of 100% after 50 cycles).
Journal ArticleDOI
Review on composite polymer electrolytes for lithium batteries
A. Manuel Stephan,KeeSuk Nahm +1 more
TL;DR: In this paper, the state of the art of composite polymer electrolytes (CPE) in view of their electrochemical and physical properties for the applications in lithium batteries is reviewed.
References
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Journal ArticleDOI
Nanocomposite polymer electrolytes for lithium batteries
TL;DR: In this article, the authors showed that nanometre-sized ceramic powders can be used as solid plasticizers for polyethylene oxide (PEO) electrolytes to prevent crystallization on annealing from amorphous state above 60°C.
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Physical and chemical properties of nanocomposite polymer electrolytes
Fausto Croce,Roberta Curini,Andrea Martinelli,L Persi,Fabio Ronci,Bruno Scrosati,Ruggero Caminiti +6 more
TL;DR: The physical and chemical properties of a new class of lithium conducting polymer electrolytes formed by dispersing ceramic powders at the nanoscale particle size into a poly(ethylenoxide) (PEO)− lithium salt, LiX complexes, are reported and discussed in this paper.
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Transport and interfacial properties of composite polymer electrolytes
TL;DR: In this article, the authors demonstrate that a successful approach for overcoming these problems, is the dispersion of selected ceramic powders in the polymer mass, with the aim of developing new types of composite PEO-LiX polymer electrolytes characterized by enhanced interfacial stability, as well as by improved ambient temperature transport properties.
Journal ArticleDOI
Effects of nanoscale SiO2 on the thermal and transport properties of solvent-free, poly(ethylene oxide) (PEO)-based polymer electrolytes
TL;DR: In this article, a composite electrolyte based on poly(ethylene oxide) (PEO) has been prepared by using LiClO4 and LiN(CF3SO2)2 as doping salts, and nanoscale SiO2 as the filler.