Journal ArticleDOI
Semibridging interactions and conformational equilibria in methoxymethylidyne cluster complexes. Syntheses, spectroscopic, and x-ray crystallographic studies on CoFe2(.mu.-H)(.mu.3-COCH3)(CO)7(.eta.-C5H5), Fe2Ni(.mu.3-COCH3)(.mu.3-CO)(CO)6(.eta.-C5H5), and AuCoFe2(.mu.3-COCH3)(.mu.3-CO)(CO)6(PPh3)(.eta.-C5H5)
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This article is published in Organometallics.The article was published on 1986-06-01. It has received 21 citations till now.read more
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Journal ArticleDOI
Phosphorus Copies of PPV: π-Conjugated Polymers and Molecules Composed of Alternating Phenylene and Phosphaalkene Moieties
TL;DR: Remarkably, selective Z-isomer formation (i.e., trans arylene moieties) is observed for PPPs when bulky P-substituents are employed while E/Z-mixtures are otherwise obtained.
Journal ArticleDOI
Metal−Metal and Metal−Ligand Bonding at a QTAIM Catastrophe: A Combined Experimental and Theoretical Charge Density Study on the Alkylidyne Cluster Fe3(μ-H)(μ-COMe)(CO)10
TL;DR: Theoretical studies using the Electron Localizability Indicator (ELI-D) suggest the metal-metal bonding is more significant, while the delocalization indices imply that both Fe-Fe bonding and Fe···C(alkylidyne) bonding are equally important.
Book ChapterDOI
Heteronuclear Cluster Chemistry of Copper, Silver, and Gold
TL;DR: In this article, the synthesis, structures, chemical properties, and dynamic behavior of Group IB metal heteronuclear cluster compounds are reviewed. But the majority of these compounds do not carry any ligands or with ligands that are not simple two-electron donors bonded to the Group IB metals.
Book ChapterDOI
Heteronuclear Gold Cluster Compounds
TL;DR: The development of the area of heteronuclear gold cluster chemistry can be traced to the pioneering work of Lewis and Nyholm, who reported the first syntheses and crystallographic determinations of compounds, containing gold-metal bonds in a series of articles from 1964 onward.
Journal ArticleDOI
Protonation Reactions on the Binuclear Complexes [W2Cp2(CO)n(μ-L2)] [L2 = Ph2PCH2PPh2, Me2PCH2PMe2; n = 2, 4]. Chemical Behavior of Their Hydrido and Hydroxycarbyne Derivatives
TL;DR: In this paper, it was shown that the relative amounts of the above products in the reaction mixtures depend both on the nature of L 2 and reaction conditions, and when L 2 = Me2PCH2PMe2, the above O-protonation competes with direct proton attack at the intermetallic bond, t...