Journal ArticleDOI
Square planar silver(I) complexes: A rare but increasingly observed stereochemistry for silver(I)
Aidan G. Young,Lyall R. Hanton +1 more
TLDR
The square planar Ag(I) ion is a rare ion, with only ∼2% of all reported silver complexes possessing this stereochemistry as discussed by the authors, despite the fact that there are currently around 65 well characterised complexes containing squareplanar Ag (I) ions, about half of which are coordination polymers.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 204 citations till now.read more
Citations
More filters
Journal ArticleDOI
A multicomponent CuAAC “click” approach to a library of hybrid polydentate 2-pyridyl-1,2,3-triazole ligands: new building blocks for the generation of metallosupramolecular architectures
TL;DR: It is found, using HR-ESMS, (1)H NMR, and X-ray crystallography, that both discrete and polymeric metallosupramolecular architectures can be formed.
Journal ArticleDOI
A one pot multi-component CuAAC “click” approach to bidentate and tridentate pyridyl-1,2,3-triazole ligands: Synthesis, X-ray structures and copper(II) and silver(I) complexes
TL;DR: In this paper, a one pot, multi-component CuAAC reaction has been developed for the generation of alkyl, benzyl or aryl substituted bi and tridentate pyridyl-1,2,3-triazole ligands from their corresponding halides, sodium azide and alkynes in excellent yields.
Journal ArticleDOI
From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields.
Roald Hoffmann,Santiago Alvarez,Carlo Mealli,Andrés Falceto,Thomas J. Cahill,Tao Zeng,Gabriele Manca +6 more
TL;DR: In this article, a brief review of the development of the normal ordering of nd orbitals of transition metal interacting with ligands is given, with the most common cases being three below two in an octahedral environment, two below three in tetrahedral coordination, and four below one in a square-planar environment.
Journal ArticleDOI
Deciphering synergetic core-shell transformation from [Mo 6 O 22 @Ag 44 ] to [Mo 8 O 28 @Ag 50 ].
TL;DR: Mass spectrometry is used to reveal an acid-induced structural transformation between two Ag clusters that proceeds via a breakage-growth-reassembly mechanism and helps to better understand the complex transformation process underpinning the assembly system.
Journal ArticleDOI
Solvent or temperature induced diverse coordination polymers of silver(I) sulfate and bipyrazole systems: syntheses, crystal structures, luminescence, and sorption properties.
TL;DR: Three new coordination polymers have been solvothermally synthesized with Ag2SO4 and flexible ligand 3,3',5,5'-tetramethyl-4,4'-bipyrazole (H2bpz) in different solvents and temperatures, affording an unprecedented 2D + 2 D + 2D → 3D polycatenating cationic framework with 1D + 3D porous systems.
References
More filters
Journal ArticleDOI
Bond‐valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database
I. D. Brown,D. Altermatt +1 more
Journal ArticleDOI
Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, tau4.
TL;DR: A new geometric parameter for four-coordinate compounds, tau(4), is proposed as an improved, simple metric for quantitatively evaluating the geometry of four- coordinate complexes and compounds.
Journal ArticleDOI
New Self-Assembled Structural Motifs in Coordination Chemistry.
Journal ArticleDOI
CH/π hydrogen bonds in crystals
TL;DR: The CH/π interaction is a kind of hydrogen bond operating between a soft acid CH and a soft base π-system (double and triple bonds, C6 and C5 aromatic rings, heteroaromatics, convex surfaces of fullerenes and nanotubes) as discussed by the authors.