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Structural and property studies of high Zr-content lead zirconate titanate

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TLDR
In this article, a transition between a disordered R-type tilted state to a low temperature ordered R- type tilted state was found near the FER(HT)-FER(LT) boundary.
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This article is published in Journal of Physics and Chemistry of Solids.The article was published on 1996-10-01. It has received 44 citations till now. The article focuses on the topics: Lead zirconate titanate & Ferroelectricity.

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Citations
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Octahedral tilt-suppression of ferroelectric domain wall dynamics and the associated piezoelectric activity in Pb ( Zr , Ti ) O 3

TL;DR: In this paper, the authors applied Rayleigh law analysis to access the relative extrinsic domain wall contributions to the nonlinear permittivity and converse piezoelectric properties.
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Effects of Octahedral Tilting on the Piezoelectric Properties of Strontium/Barium/Niobium‐Doped Soft Lead Zirconate Titanate Ceramics

TL;DR: In this paper, the authors investigated the relationship between structural changes caused by isovalent strontium and barium substitution on the A-site and dielectric and piezoelectric properties.
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High energy density at high temperature in PLZST antiferroelectric ceramics

TL;DR: In this paper, the authors showed that orthorhombic to tetragonal phase transition behavior and the high TC point of O3 O3 ceramics can achieve high energy density (2.0 − 3.4 J cm−3) at high temperature (100 −175 °C) rather than room temperature.
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Octahedral tilting, monoclinic phase and the phase diagram of PZT.

TL;DR: Anelastic and dielectric spectroscopy measurements on PbZr1−xTixO3 (PZT) close to the morphotropic (MPB) and antiferroelectric boundaries provide new insight into some controversial aspects of its phase diagram as discussed by the authors.
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Toward Decoding the Relationship between Domain Structure and Functionality in Ferroelectrics via Hidden Latent Variables.

TL;DR: This approach provides a workflow to establish the presence of correlation between local spectral responses and local structure and can be universally applied to spectral imaging techniques such as piezoresponse force microscopy (PFM), scanning tunneling microscopy and spectroscopy, and electron energy lossSpectroscopy in scanning transmission electron microscope (STEM).
References
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Dielectric properties of tetragonal lanthanum modified lead zirconate titanate ceramics

TL;DR: Tetragonal La-modified lead zirconate titanate ceramics with a Zr/Ti ratio of 40/60 (x/40/60) with La contents (x) between 0 and 21 at.
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Atomic structures of two rhombohedral ferroelectric phases in the Pb(Zr, Ti)O3 solid solution series☆

TL;DR: The atomic positions in perovskitic PbZr x Ti 1− x O 3 were determined for x = 0.9 and X-ray and neutron diffraction.
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Transmission electron microscopy study of high-Zr-content lead zirconate titanate.

TL;DR: Transmission electron microscopy studies revealed an intermediate ferroelectric phase with rhombohedral symmetry between low-temperature antiferroelectric orthorhombic and high-tem temperature paraelectric cubic states, and it is believed that a hierarchy of symmetries exists over a wide region of therhombohedral ferro electric phase field.
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A Study of Structural Phase Transitions in Antiferroelectric PbZrO3 by Neutron Diffraction

TL;DR: In this article, temperature dependence of neutron diffraction intensities of PbZrO 3 was measured in the room-temperature antiferroelectric phase and the crystal structure was found to be described by a sum of modulations associated with lattice vibrational modes Σ 3, R 25 x and R 25 y.
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Evidence for a New Phase Boundary in the Ferroelectric Lead Zirconate‐Lead Titanate System

TL;DR: In this paper, a phase diagram of the lead zirconate-lead titanate system with 1 wt% NbO/sub 5/ is presented, and a hysteresis anomaly occurs in dissipation and dielectric constant measurements as functions of temperature and effects on the planar coupling coefficient and the resistivity.
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