Journal ArticleDOI
Structural, spectroscopic and thermal characterization of 2-tert-butylaminomethylpyridine-6-carboxylic acid methylester and its Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and UO(2)(II) complexes.
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TLDR
In this paper, a terdentate ligand with the ligand 2-tert-butylaminomethylpyridine-6-carboxylic acid methylester (HL(2)) has been characterized by elemental analyses, molar conductance, magnetic moment, thermal analysis and spectral data.About:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 2005-04-01. It has received 17 citations till now. The article focuses on the topics: Carboxylate.read more
Citations
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Optimization of the arsenazo-III method for the determination of uranium in water and plant samples
Loïc Jauberty,Nicolas Drogat,Jean-Louis Decossas,Vincent Delpech,Vincent Gloaguen,Vincent Sol +5 more
TL;DR: It is demonstrated that the present technique is able to precisely quantify uranium in water as well as in plant samples, within the μg/L and mg/g ranges respectively.
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Preparation and spectroscopic characterization of novel cyclodiphosph(V)azane of N(1)-2-pyrimidinylsulfanilamide complexes. Magnetic, thermal and biological activity studies
TL;DR: The spectral data reveal that all the ligands behave as neutral bidentate ligands and coordinated to the metal ions via pyrimidine-N and enolic sulfonamide OH while UV-vis, solid reflectance and magnetic moment data have been shown that the complexes have octahedral geometry.
Journal ArticleDOI
Chiral copper–bipyridine complexes: Synthesis, characterization and mechanistic studies on asymmetric cyclopropanation
TL;DR: In this article, the triflate derivatives of both the Cu(I) and Cu(II) complexes are active catalysts towards the cyclopropanation of ethyl diazoacetate with styrene.
Journal ArticleDOI
Coordination behaviour and biopotency of metal NN salen complexes
TL;DR: The results revealed that coordination may be considered as an interesting strategy to significantly reduce the cytotoxic dose, which may help to overcome the limitations of use of any metal and to understand their metabolism in living beings.
Journal ArticleDOI
Design and synthesis of novel complexes containing N-phenyl-1H-pyrazole moiety: Ni complex as potential antifungal and antiproliferative compound
TL;DR: Both of the capability as a potent in vitro antifungal agent and the cell test analysis show Ni(II) complex (2) as a promising material in the translation of observed in vitro biological phenomenon into clinical therapies settings.
References
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
Novel olefin polymerization catalysts based on iron and cobalt
George J. P. Britovsek,Vernon C. Gibson,Stuart James Mctavish,Gregory A. Solan,Andrew J. P. White,David J. Williams,Brian Stephen Kimberley,Peter James Maddox +7 more
TL;DR: A new family of olefin polymerization catalysts, derived from iron and cobalt complexes bearing 2,6-bis(imino)pyridyl ligands, was described in this paper.
Journal ArticleDOI
Normal Vibrations of N‐Methylacetamide
TL;DR: In this paper, the inplane normal vibrations of Nmethylacetamide and its deuterated compound were calculated as a six-body problem and the normal modes as well as the distributions of the potential energy among symmetry coordinates were also calculated.
Journal ArticleDOI
Mechanisms of d8 organometallic reactions involving electrophiles and intramolecular assistance by nucleophiles
Allan J. Canty,G. van Koten +1 more
TL;DR: The most attractive and fundamental interaction between metal centers and organic molecules that could lead to new functionalization at carbon is direct activation of the C-H bonds of hydrocarbons as discussed by the authors.
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