Journal ArticleDOI
Synthesis and crystal structure of a chiral two-dimensional metal-organic coordination polymer: (S-(-)-lactate) (isonicotinato)zinc(II)
TLDR
In this paper, the synthesis and X-ray characterization of the first example of an L-lactic acid two-dimensional metal coordination polymer with an additional bridging ligand was reported.Abstract:
The synthesis and X-ray characterization of the first example of an L-lactic acid two-dimensional metal coordination polymer with an additional bridging ligand, (S-(-)-lactate)(isonicotinato)zinc(II), (S-µ-2-hydroxypropanoinato)zinc(II), 1 is reported. It crystallizes in the acentric orthorhombic space group P212121 and displays powder SHG efficiencies ca. 1.2 times that of urea.read more
Citations
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Rational synthesis of noncentrosymmetric metal-organic frameworks for second-order nonlinear optics.
Cheng Wang,Teng Zhang,Wenbin Lin +2 more
TL;DR: The term nonlinear optics (NLO) was coined to describe the nonlinear relationship between dielectric polarization P and electric field E in optical media to develop materials with the ability to alter the frequency of light, to amplify light signal, and to modulate light intensity or phase factors.
Journal ArticleDOI
Structures and properties of Zn(II) coordination polymers
TL;DR: The properties and properties of coordination polymers derived from Zn(II) and polydentate organic ligands are reviewed in this paper, where a wide variety of structures ranging from simple 1D infinite chains to robust, porous 3D frameworks are discussed.
Journal ArticleDOI
Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications.
TL;DR: In this article, the authors provide an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.
Journal ArticleDOI
A second-order nonlinear optical material prepared through in situ hydrothermal ligand synthesis.
TL;DR: Among the three new complexes, 3 shows the largest SHG effect, which is about 50 and 500 times that of urea and KDP (KH(2)PO(4)), respectively, and the two-center-A-D system (multicenter push-pull electronic effect) in 3 may be responsible for it having the largestSHG effect.
Journal ArticleDOI
Homochiral Zn and Cd coordination polymers containing amino acid-tetrazole ligands.
Zhi-Rong Qu,Hong Zhao,Xi-Sen Wang,Yong-Hua Li,Yu-Mei Song,Yujuan Liu,Qiong Ye,Ren-Gen Xiong,Brendan F. Abrahams,Zi-Ling Xue,Xiao-Zeng You +10 more
TL;DR: The reactions of (S)-3-cyanophenylalanine with NaN(3) in the presence of H(2)O and Lewis acids and ZnCl and CdCl afford two unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II)
References
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Journal ArticleDOI
A Powder Technique for the Evaluation of Nonlinear Optical Materials
S. Kurtz,T. T. Perry +1 more
TL;DR: In this article, an experimental technique using powders is described which permits the rapid classification of materials according to the magnitude of nonlinear optical coefficients relative to a crystalline quartz standard and the existence or absence of phase matching direction(s) for second-harmonic generation.
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Crystal Engineering of Acentric Diamondoid Metal–Organic Coordination Networks
TL;DR: Acentric three-dimensional coordination polymers bis(isonicotinato)zinc and bis(4-pyridylacrylato)cadmium⋅H2 O (2) were synthesized under hydro(solvo)thermal conditions and exhibit remarkable thermal stability.
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